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- 1. A student synthesized 3.214g of Ni(NH3)„Cl2 from 4.023g of N¡C12•6H2O. He dissolved 0.81g of Ni(NH3)nCl2 in 40 mL of 1.0M HCI to make a sample for analysis. Molar mass: Ni 58.7; Cl2 71; NH3 1T; H2O 18. (1) A 0.20M Ni²* standard solution had an absorbance of 1.666, while his sample had an absorbance of 0.705. Calculate the Ni2+ concentration in his sample and the mass percent of Ni in the product. Note: A = ɛbc. (2) The student used 38.75 mL of 0.498M NaOH to neutralize excess HCl in 40mL of the sample. Calculate the mass percent of NH3 in the product.6:34 PM Fri Oct 8 AA A www-awn.aleks.com G periodic table -. D Favorites - YouT... TV fuboTV - Watch... XA ALEKS - Caliyah... G kno3 acid or ba... G linear program... G write formulas f... C O CHEMICAL REACTIONS Predicting precipitation Caliya Complete the table below by deciding whether a precipitate forms when aqueous solutions A and B are mixed. If a precipitate will form, enter its empirical formula in the last column. Does a empirical formula of precipitate form solution A solution B when A and B precipitate are mixed? zinc nitrate O yes O no ammonium sulfide sodium hydroxide O yes O no ammonium bromide sodium iodide O yes O no lead(II) nitrate II3 Bal, (aq)+ 2 Nag POq Caq) 7 BalPO42 + l6 Nal laq • Consider the reaction of 30.0mL of 0.270M Balz with 20.0 mL of 0.3ISM Naz PO4. Lwhat quantity in meles of Balz are preset in the solution? are produced /What quantitg in moles of precipitate E ali Bal were consumed based on the balanced chomical equation? 6) What auantity in males of Na3 Pla aro present in soluction? d) What quantity in moles of precipitate are paduced if all the Naz PO, were cansumed based on the balanced chemi.cal equation? e) which reactant is limisting f What mass (in g) of precipitate is firemed when the limiting reactant is considered?
- Write all the reactions involved in the Mohr's method, if an unknown solution containing chloride ions is titrated against silver nitrate solution. Suggest an indicator and what is its colourin the unknown chloride solution ? and Why is KSCN solution used as burette solution and not in conical flask in Volhard's method?A 600.0 mg sample consist only of CaC2O4 and MgC2O4 was heated at 500°C converting the two salts to CaCO3 and MgCO3. The resulting precipitate weighed 465.0 mg. If the sample had been heated at 900°C, the products would be CaO and MgO, what would the mixture of oxides weigh? (FW: CaC2O4=128.1; MgC2O4=112.3; CaCO3=100.1; MgCO3=84.31; CaO=56.08; MgO=40.31)(6) Calculate the numbeT of moles of HNO, reacting when 50.0 mL of 1.00M HNO, and 50.5 mL of 1.00M NaOH solution are mixed. (7) Calculate AHneutza in joules per mole for the reaction of 1.00 mol of HNO3 with 1.00 mol of NaOH. (8) On the basis of an accepted AHneutzn of 58.5 kJ mol' for the reaction, determine the percent error in your calculated AHneutan. +
- 5.) Calculate the volume, in liters, of NaOH required to titrate the KHP in flask #2. (A7) – (A6) Volume of NaOH = 1000 mL/L 16.36 O.80 (A14) 1000 mL/L ||(f) Potassium permanganate (g) Sodium hypochlorite (h) Beryllium bicarbonate (1) Ammonium dichromate (G) Iron (II) chlorideWrite the expression Kc for the following reactions. (a) Fe2+(aq) + Ce4+(aq) ⇋ Fe3+(aq) + Ce3+(aq) (b) CaCO3(s) ⇋ CaO(s) + CO3(g)
- Experiment-A8: Spectrophotometry of Cobalt( Pre-laboratory Exercises 1. (a) Define Beer's law and give the mathematical equation (specify each symbol in the equation). concentration of achemical Solution Beer's Law states that the in the following A = Ebc is directly proportional to its absorption of light & can be calculated formula (b) Briefly explain what Beer's plot is and how do you obtain the Beer's constant (k) from the plot. is a straight line with _ay-intercept Beer's plot of zero & a slope of ab oreb. It represents the absorptunity the length Absorbance 8 can be calculate by multiplying Constant by the path length then dinding that value by the 2. The following solutions are prepared from 0.200 MNICI, and their absorbance measured at 725 nm. Solution # 1 2 3 4 5 Volume (mL) of 0.200 M NiCh 1.00 2.00 3.00 4.00 pride 5.00 Volume (mL) of H₂O 4.00 3.00 2.00 1.00 0.00 INICI] (a) Calculate the molar concentration of NiCl₂ in each solution 1-5. Absorbance at 725 nm 0.105 0.210 0.315…Agency TEXAS UNITED REALTY Real Estate 75 g u cup increases by 2.44 70 V the heat change per mole of Cich dissolved in water Assame that all the heat is absorbed ed E. D 1 15) When aqueous solutions of Pb(NO3)2 and NaCl are mixed, PbCl2 precipitates. The balanced net ionic equation is: O to slom to slom I asdW (SC flot sdi of gaibros (2)OsH bas (2)5¹1 mot Pb2+ (aq) + 2C1- (aq) → PbCl2 (s) prisupe Pb2+ (aq) + 2NO3- (aq) → Pb(NO3)2 (s) H Pb2+ (aq) + 2NO3- (aq) -> Pb(NO3)2 (aq) Pb(NO3)2 (aq) + 2NaCl (aq) → PbCl2 (aq) + 2NaNO3 (s) laubonHow many grams of NaOH must be added to a 1.00 L aqueous solution containing 2.00 g of NiCl to fully remove the nickel (II) cation from the solution in the form of a Ni(OH)2 precipitate? • Your answer should have three significant figures (round to the nearest hundredth).