1. Assign priorities to these set of Substituentsа. -ОН, -СН2CH3 ,-CH=CH2-OCH2CH3b. -NH2-NO2-NHCH3 ,-C=Nс. -СH2CH3-CH2SH , -CH(CH3)2-C=CHd.CHCOCH3-coČCH3e. -CH(CH3)2 , -C(CH3)3 , -CH2CH(CH3)2 ,-CH2C(CH3)3f. -OCI , -NHCI-OBr-NHB.End of document I

Assignment of priority to substituent is done according to cahn, ingold ,Prelog Cahn, Ingold, Prelog…

Answered: 1. Assign priorities to these set of…

1. Assign priorities to these set of Substituents a. -OH, -CH2CH3 , -CH=CH2 , -OCH2CH3 b. -NH2 , -NO2 -NHCH3 , -CEN c. -CH2CH3 -CH2SH , -CH(CH3)2 -C=CH

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter4: Organic Compounds: Cycloalkanes And Their Stereochemistry

Section4.SE: Something Extra

Problem 35AP: A 1, 2-cis disubstituted cyclohexane, such as cis-1, 2-dichlorocyclohexane, must have one group...

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Concept explainers

Reactive Intermediates

In chemistry, reactive intermediates are termed as short-lived, highly reactive atoms with high energy. They rapidly transform into stable particles during a chemical reaction. In specific cases, by means of matrix isolation and at low-temperature reactive intermediates can be isolated.

Hydride Shift

A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carbocation to attain stability in the compound. Such structural reorganization movement is called a shift within molecules. After the shifting of carbocation over the different carbon then they form structural isomers of the previous existing molecule.

Vinylic Carbocation

A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond therefore it is sp hybridized. It is known to be a part of various reactions, for example, electrophilic addition of alkynes and solvolysis as well. It plays the role of a reactive intermediate in these reactions.

Cycloheptatrienyl Cation

It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthesized from tropine.

Stability of Vinyl Carbocation

Carbocations are positively charged carbon atoms. It is also known as a carbonium ion.

Question

1. Assign priorities to these set of Substituents
а. -ОН, -СН2CH3 ,
-CH=CH2
-OCH2CH3
b. -NH2
-NO2
-NHCH3 ,
-C=N
с. -СH2CH3
-CH2SH , -CH(CH3)2
-C=CH
d.
CH
COCH3
-coČCH3
e. -CH(CH3)2 , -C(CH3)3 , -CH2CH(CH3)2 ,-CH2C(CH3)3
f. -OCI , -NHCI
-OBr
-NHB.
End of document I

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