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- = 8. The following is a Frost diagram of phosphorus in aqueous solution at pH 0. Specify the form of P that is: (i) the most thermodynamically stable; (ii) the least thermodynamically stable; (iii) unstable and will disproportionate, also specify the new forms that will be made. ZE°/V 0.5 0.0 -0.5 -1.0 -1.5 -2.0 PH3 H3PO₂ -2.5 -3 -2 -1 0 1 2 3 H3PO3 H3PO4 4 5 Oxidation state, NTiame tests, the yello w colour oT sodium lons can mask the coIour of otner lons. Explain why blue glass is used to ldentity ions in the presence of sodium. Saved Normal B|I|U fx | | D E li Delete columnThe mean activity coefficient in an 0.050 molKg-1 LaCl3 (aq) solutions is 0.303 at 25 o C. What is the percentage error in the value predicted by the debye – Huckel limiting law?
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- 1. Calculate the normal freezing point of a 0.7439 mol aqueous solution of C12H22O11 that has a density of 1.35 g/ml. (C12H22O11 is a non-volatile non-dissociating solute.) The molal freezing point depression constant of water is 1.86OC kg/mole. 2. When 0.279 g of a molecular compound, benzoic acid, was dissolvedin 43.0 g of benzene, the freezing point of the solution was lowered to5.15 °C. What is the molecular weight of the benzoic acid? (Note: Kf forbenzene = 5.120C/m; Freezing point of benzene= 5.50C)An alkaline sample of sodium compounds weighing 1.196 g was dissolved in water, cooled at 15 deg C, treated with 2 drops of phenolphthalein indicator and titrated with 1.058 N H2SO4 requiring 6.8 mL to render the solution colorless. Upon adding 2 drops of methyl orange and continuing the titration 16.5 mL more of the acid was needed to complete analysis. What is the quantitative composition of the sample?Calculate the values expected for the total alkalinity and for the phenol- phthalein alkalinity of a 25°C saturated solution of calcium carbonate in water, and compare them to the values for a solution that also is in equilib- rium with atmospheric carbon dioxide. Use the concentrations quoted in the last column of Table 10-4.