1. In aqueous solution, [Co(CN),C1]³ hydrolyses according to:[Co(CN), Cl]³¯ + H₂O → [Co(CN) (H₂O)]²¯ + CI˜¯The reaction is subject to catalysis by H†, so that:=Rate k₁ {[Co(CN), Cl]³¯}* +k₂[H*]{[Co(CN), CI]³¯}*,in which kɩ and k₂ are rate constants for the uncatalysed and catalyzed pathways, respectively.At pH = 3.00, the two pathways contribute equally to the overall rate, and the data below obtain:2030 1800.057 0.0803000.080Time (min)0 10[Co(CN),(H2O)]² (mol/L) 0 0.027 0.045a. Find the initial concentration of [Co(CN)5C1]³¯, and show that the data are consistent withx == 1.b. Evaluate k₁ and k₂.c. What is the half-life of [Co(CN)5C1]³¯ at pH = 7.00?

Given:- Reaction: [Co(CN)₅Cl]³⁻ + H₂O → [Co(CN)₅(H₂O)]²⁻ + Cl⁻- Rate = k₁[Co(CN)₅Cl³⁻] +…

Answered: 1. In aqueous solution, [Co(CN),C1]³…

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter19: Transitition Metals, Coordination Chemistry And Metallurgy

Section: Chapter Questions

Problem 19.69QE

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Calculate K1 for the reaction: Fe(s) + H2O(g) ⇔ FeO(s) + H2(g) K1 = ? given the following data: H2O(g) + CO(g) ⇔ H2(g) + CO2(g) K2 = 1.6 FeO(s) + CO(g) ⇔ Fe(s) + CO2(g) K3 = 0.67 Type your final answer to 2 decimal places.
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The Kc = 5.6 x 108 for the reaction at 25.0 C: Ni2+ (aq) + 6 NH3 (aq) Ni(NH3),2* What is the AG° in J/mol?
Chemistry Given: Ferrous ion ( Fe2+ ) is converted into ferric hydroxide solid, Fe(OH)3(s), and dichromate ion (Cr2O72-) is converted into chromium dihydroxo complex, Cr(OH)2+. _Fe2+ + _Cr2O72- => _Fe(OH)3(s) + _Cr(OH)2+ (unbalanced) Required: a) Balance this redox reaction. Required: . 1) Show calc.’s for determining oxid. state of all species that undergo a change in oxid. state. 2) Indicate total number of e-‘s stripped from each atom of reductant, and the total number accepted by each atom of the oxidizing agent. 3) show how many moles of oxidant are needed to balance e-‘s removed vs gained. 4) Remember to balance the other atoms and the charge. Assume that the reaction takes place under acidic conditions. b) Which element is the oxidizing agent (oxidant)? Reducing Agent (reductant)? c) Which element is being oxidizing? Reduced?.... Its is single question please solve it completely ?
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Rate information was obtained for the following reaction at 25°C and 33°C; Cr(H2O)6 3+ + SCN¯ ---> Cr(H2O)5NCS2+ + H2O(l) Initial Rate [Cr(H2O)6 3+] [SCN-] @ 25°C 2.0x10-11 1.0x10-4 0.10 2.0x10-10 1.0x10-3 0.10 9.0x10-10 2.0x10-3 0.15 2.4x10-9 3.0x10-3 0.20 @ 33°C 1.4x10-10 1.0x10-4 0.20 a) Write a rate law consistent with the experimental data. b) What is the value of the rate constant at 25°C? c) What is the value of the rate constant at 33°C? d) What is the activation energy for this reaction? e) Can a 4th order reaction occur?
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(f) Potassium permanganate (g) Sodium hypochlorite (h) Beryllium bicarbonate (1) Ammonium dichromate (G) Iron (II) chloride
(d) M=? [M(CO),]+ (e) M=? H3CM(CO)5

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