1. Write the organic and inorganic products of the following reactions. Indicate cis or trans, axial or equatorial, or R or S or racemic, where appropriate. If there is no reaction write NR а). Br + NaOAc acetone, solvent Br b) cis or trans product, R or S at the 2 chiral centers? CH3 Br (R) + NaN3 acetone, solvent (S) c) R or S product? Br + NaCN acetone, solvent Ph

1. Write the organic and inorganic products of the following reactions. Indicate cis or trans, axial or equatorial, or R or S or racemic, where appropriate. If there is no reaction write NR а). Br + NaOAc acetone, solvent Br b) cis or trans product, R or S at the 2 chiral centers? CH3 Br (R) + NaN3 acetone, solvent (S) c) R or S product? Br + NaCN acetone, solvent Ph

Chemistry & Chemical Reactivity

10th Edition

ISBN:9781337399074

Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Chapter23: Carbon: Not Just Another Element

Section: Chapter Questions

Problem 106IL

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Note these acronyms: HOAC = Acetic Acid; NaOAc = Sodium Acetate; THF = tetrahydrofuran Ph = Phenyl = C6H5; DMSO = Dimethyl Sulfoxide, H3C-O-H = methanol, NBS = N-Bromo succinimide, LDA =, Lithium Diisopropylamide, DIA = Diisopropyl Amine, ACN=Acetonitrile Acetone = Acetic Acid = THF= DMSO= Ph= H3C CH3 H3C HO. H3C CH3 Will the reaction conditions below favor SN2 or E2 chemistry? (Simply write SN2 or E2 on the right side of the arrow). b) Br NAOAC, ACN solvent c) Br NaN3, ACN solvent d) R= tertiary butyl Br NaOR, HOR solvent ||
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1-propanol + hydrobromic acid →