Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter17: Electrochemistry
Section: Chapter Questions
Problem 103CP
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At 25 °C and 1 bar, the emf values of a cell at various molalities, m, are given as
follows:
Pt H₂(g,P°)| HCl(aq,m) | Hg₂Cl₂(s) Hg(t)
C/m
E/V
Determine
1.6077 3.0769 5.0403 7.6938 10.9474
0.6008 0.5683 0.54366 0.52267 0.50532
(i) the standard cell potential, Eº, using a graphical method.
(ii) the mean activity coefficient, y, of HCI at the concentration 5.0403 m.
Transcribed Image Text:At 25 °C and 1 bar, the emf values of a cell at various molalities, m, are given as follows: Pt H₂(g,P°)| HCl(aq,m) | Hg₂Cl₂(s) Hg(t) C/m E/V Determine 1.6077 3.0769 5.0403 7.6938 10.9474 0.6008 0.5683 0.54366 0.52267 0.50532 (i) the standard cell potential, Eº, using a graphical method. (ii) the mean activity coefficient, y, of HCI at the concentration 5.0403 m.
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