12. Bromination of alkanes is a much slower reaction than chlorination. Which of the following is expected to be the major organic product when 2-methylbutane is allowed to react with Br₂ in the presence of light or heat? CH3 CH3CH₂CHCH3 + Br₂ light
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- IV. Complete the equations for the following reactions. Show all organic alkene products form, mechanism, indicate the major product and the rule Ş(CH3)2 NaSH HEAT OH™ HEAT6.) Predict the product of the following chemical reactions and state where the product (waste) sk waste should be disposed: Example: OH 1. NaBH4, ethanol CH;CH,CH,CH CH;CH,CH,CH 2. H3O* H Butanal 1-Butanol Waste: G704 (Non-halogenated organic solvents) 1. NaBH4, ethanol a.) Cyclohexanecarbaldehyde 2. H3O* b.) Sodium Flouride + 3-iodo-3-methylpentane (hint: substitution or eliminatic 2/3 H3O* c.) Benzoic acid + Phenol РС d.) 3-pentanol H2CrO4 e.) CyclohexylmethanolAn alkene having the molecular formula C,H12 is treated sequentially with ozone (O3) and zinc/acetic acid to give the product/s shown. CH3CH2CH,CH½CH2CH Draw a structural formula for the alkene. You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. P opy aste Previous Next
- An alkene having the molecular formula C5H10 is treated sequentially with ozone (O3) and zinc/acetic acid to give the product/s shown. H3C O CH3CHCH + H. Draw a structural formula for the alkene. You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. In cases where there is more than one answer, just draw one. P opy aste [* Previous NextWrite the mechanism(s), major product(s), and stereochemistry(ies) for each of the following reactions:please do them in the structural form i have themThe rate law for addition of Br2 to an alkene is first orderin Br2 and first order in the alkene. Does this informationsuggest that the mechanism of addition of Br2 to analkene proceeds in the same manner as for addition of HBr?Explain.
- Two substitution products result from the reaction between 3-chloro-3-methyl-1- butene with sodium acetate (CH3COO – Na +) in acetic acid under SN1. Identify the products.The compound below is treated with chlorine in the presence of light. CH3 CH3 CH3 Draw the structure for the organic radical species produced by reaction of the compound with a chlorine atom. Assume reaction occurs at the weakest C-H bond. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. Sn [F ?Predict the organic product of the reaction of 2-butene with each reagent. You do not have to consider stereochemistry. In cases where there is more than one answer, just draw one. • Omit lone pairs and radical electrons from your answer. (a) Br₂ (b) H₂O (H₂SO4) ** ***** 24 Sn [F ChemDoodle 好 Sn [F
- (d) When butane, CH3CH2CH2CH3 and bromine gas, Br2 is exposed to sunlight, monobrominated product are produced. The reaction equation is given below: uv CH;CH,CH,CH3 + Br2 A + B (i) State the type of reaction. (ii) What is the function of the sunlight in the reaction? (iii) Draw the structure of monosubstituted products, A and B. Label the major product. (iv) Draw the propagation steps in the mechanism for the formation of the major product.11.; (a) Similar to alkanes, hydrogen gas can undergo radical bromination according to the reaction below. Propose a chain-reaction mechanism for this reaction, including an initiation step, propagation steps, and two plausible termination steps. The homolytic bond dissociation energy for Br-Br is 46 kcal·mole', for H-Br is 88 kcal'mole and for H-H is 104 kcal'mole'. hv H-H + Br-Br 2 H-Br (b) Calculate the overall AH for the above propagation steps (show all work).The structure below is the cyclic ether (epoxide), butene oxide: (1) CH3CH₂ -CH₂ butene oxide How could this compound be prepared from but-1-ene? Explain why butene oxide is much more reactive than its isomer, tetrahydrofuran, which is also a cyclic ether: H₂C-CH₂ H₂C CH₂ tetrahydrofuran Illustrate how butene oxide reacts with ammonia, showing details of the mechanism leading to the final product, C4H11 NO.