15. Suppose that we titrate 100.0 mL of 0.050 0 M Fe²+ with 0.100 M Ce*“, using the cell as shown here. The equivalence point occurs when V=50.00 mL The titration reaction: Ce4++ Fe²+ Buret containing Ce** V Ce+ + Fe+ E° (Ce**/Ce³*) = 1.70 V; E° (Fe³*/Fe²+) = 0.767 V, EsCE= 0.241 V Calculate the cell voltage at 66.0 mL of Ce**. Calomel reference electrode Pt wire Fe* in 1 M HCIO, Magnetic stirring bar

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter23: Potentiometry
Section: Chapter Questions
Problem 23.24QAP
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15. Suppose that we titrate 100.0 mL of 0.050 0 M Fe²+ with 0.100 M
Ce*“, using the cell as shown here. The equivalence point occurs when
V=50.00 mL
The titration reaction: Ce4++ Fe²+
Buret containing Ce**
V
Ce+ + Fe+
E° (Ce**/Ce³*) = 1.70 V; E° (Fe³*/Fe²+) = 0.767 V, EsCE= 0.241 V
Calculate the cell voltage at 66.0 mL of Ce**.
Calomel
reference
electrode
Pt wire
Fe* in
1 M HCIO,
Magnetic
stirring bar
Transcribed Image Text:15. Suppose that we titrate 100.0 mL of 0.050 0 M Fe²+ with 0.100 M Ce*“, using the cell as shown here. The equivalence point occurs when V=50.00 mL The titration reaction: Ce4++ Fe²+ Buret containing Ce** V Ce+ + Fe+ E° (Ce**/Ce³*) = 1.70 V; E° (Fe³*/Fe²+) = 0.767 V, EsCE= 0.241 V Calculate the cell voltage at 66.0 mL of Ce**. Calomel reference electrode Pt wire Fe* in 1 M HCIO, Magnetic stirring bar
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