17). What is the product of the following Acetoacetic Ester Synthesis?glangem(A)OHOEt 1). 1 eqiv. NaOEt 2). 1 equiv. CH3CH₂Br(B)CH3(C).OHCH33). H3O+, then Heat(D)(E)OEtHOOEt

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Answered: 17). What is the product of the…

17). What is the product of the following Acetoacetic Ester Synthesis? fl (A) OEt 1). 1 eqiv. NaOEt 2). 1 equiv. CH3CH₂Br OH (B) CH3 (C) -OH CH3 3). H3O+, then Heat (D) ? (E) OEt HO OEt

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter24: Amines And Heterocycles

Section24.SE: Something Extra

Problem 75AP

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Concept explainers

Reactions at the Alpha Carbon Atom

The position next to the ketone or aldehyde functional group is termed as alpha position and the reaction which occurs at alpha position is called alpha substitution reaction. In an alpha substitution reaction, the alpha proton atom is substituted by an electrophile by the formation of an enol intermediate or enolate ion intermediate. Most of the carbonyl compounds go through an alpha substitution reaction.

Question

17). What is the product of the following Acetoacetic Ester Synthesis?
glan
gem
(A)
OH
OEt 1). 1 eqiv. NaOEt 2). 1 equiv. CH3CH₂Br
(B)
CH3
(C)
.OH
CH3
3). H3O+, then Heat
(D)
(E)
OEt
HO
OEt

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