19. Which of the equation below is (arc) appropriate for the laboratory preparation of the Hydrogen halide indicated? NaCla + H2S0,(conc.)- NaliSO,(aq) + HCIe) NaCls + H,PO,(conc.)- NaH, PO,(a) + HCle) 2. Nalsy + H,SO,(aq)(conc) NaHSO(ag) + Hl)
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Answer Q19, 20, 21
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- Ql is dissolved in 250 ml, what is the tutul normadily of A Sada- Lime Sample is go% NaoH and 10% CaO • If 3gm the Selution as abase ? How many milliliters of O.57 N H2 S4 would be requiresd to titrate 100 me of the Solution ? Ans.s (0.309 N, 60.59 ml)H.W 1) Calculate the number of meq. of H;C:O..2H;0 (fw= 126.1) in 0.5 gm of the pure compound assuming that two hydrogen ions to titrated with standard base? 2) A standard AGNO, solution prepared by weighting exactly 24.15 gm of carefully prepared solid, dissolving in water and diluting in a volumetric flask to exactly 2 L. What normality of the solution?A 4.912-g sample of a petroleum product was burnedin a tube furnace, and the SO2produced was collectedin 3% H2O2.Reaction:SO2(g)+H2O2→H2SO4A 25.00-mL portion of 0.00873 M NaOH was introducedinto the solution of H2SO4, following whichthe excess base was back-titrated with 15.17 mL of0.01102 M HCl. Calculate the sulfur concentrationin the sample in parts per million.
- E. Analysis of a mixture consisting of NaOH + NażCO3 + inert matter gives the following data: Sample portions are titrated. With one portion, an end point with phenolphthalein is obtained in cold solution, with 44.52 mL of 0.5000 N HCI. The other portion requires 46.53 mL of the acid for an end point with methyl orange. Calculate the percentage composition of the original sample. 10.00 g. Its aqueous solution is diluted to 250.0 mL and two separate 25.00 mLWhat are the respective concentrations (M) of Fe3+ and I- afforded by dissolving 0.200 mol FeI3 in water and diluting to 725 mL? A) 0.276 and 0.828 B) 0.828 and 0.276 C) 0.276 and 0.276 D) 0.145 and 0.435In this activity, you will develop an experimental procedure to solve a problem. Consider the followingscenario:You are the manager of a chemical stockroom, and find a bottle containing approximately one liter of aclear and colorless solution of unknown identity and concentration. Your only clue to its identity is thatit was found between bottles of silver fluoride and sodium fluoride, so it is likely an aqueous solution ofone of those two compounds. You will need to develop a procedure to determine the following:a) The identity of the unknown solutionb) The concentration of the unknown solutionWrite out a precise procedure, which includes all glassware, reagents, and steps. You will also need towrite the calculations that you would need to determine the concentration of the solution. Assume thatyou have access to any reagent you might need
- A mixture of NaBr, Nal and NaNO3 weighs 0.6500 g. With AgNO3, a precipitate of the two halides is obtained and is found to weigh 0.9390 g. When heated in a current of C2, the precipitate is converted entirely to AgCi weighing 0.6566 g. What is the %NaNO3 in the original sample?A sample of impure tin of mass 0.535 g is dissolved in strong acidto give a solution of Sn2+. The solution is then titrated with a0.0448 M solution of NO3-, which is reduced to NO(g). Theequivalence point is reached upon the addition of 0.0344 L of theNO3- solution. Find the percent by mass of tin in the originalsample, assuming that it contains no other reducing agents.The ascorbic acid, C,H;Os (176.124 g/mmol) content of a bottle of peach juice containing 2.50 L was determined by titration with a standard solution of potassium iodate, KIO3. The KIO; solution was prepared by dissolving 100.4 mg primary standard grade KIO; (214.001 mg/mmol) to a final volume of 250.0 mL. To a 200.00-mL aliquot of the sample, 10 mL of KI, 10 mL of HCl and 5 mL of starch solution were added and subsequently titrated, requiring 18.19 mL of the KIO; titrant. The relevant reactions are given below: KIO; + 5KI + 6H* → 3l2 + 6K* + 3H;0 CH;O, + l2→ CH,O, + 21- + 2H* a. How many millimoles of ascorbic acid is in the titrated sample? b. What is the mass of ascorbic acid per bottle of the peach juice?
- Complete the balanced chemical reaction for the following weak base with a strong acid. In this case, write the resulting acid and base as its own species in the reaction. CH;NH2(aq) + HCIO3(aq) > 4- 3. 2+ 3+ 4+ 1 2 6 7 8 O2 4 5. ) (s) (1) (g) (aq) H N H30* CI H20 OH 4- +Give the summary of reaction and rationalization of each samples.Complete and balance the following reactions. Don’t worry about state symbols for the second one. a. CoCl2(aq) + Na2S(aq) --> b. H3AsO3 + RbOH -->