2. A student prepares a solution of H3PO4 and wishes to determine its precise concentration. A 25.0 ml. sample of the H3PO4 is titrated with a standardized 0.073 M NaOH solution. The titration requires 36.4 mL of the NaOH solution to reach the equivalence point. A) Write the balanced equation between H3PO4 and NaOH. H3PO4 (aa)+ NaOH B) How many moles of NaOH were needed to reach the equivalence point? C) What is the molarity of the H3PO4 solution?

2. A student prepares a solution of H3PO4 and wishes to determine its precise concentration. A 25.0 ml. sample of the H3PO4 is titrated with a standardized 0.073 M NaOH solution. The titration requires 36.4 mL of the NaOH solution to reach the equivalence point. A) Write the balanced equation between H3PO4 and NaOH. H3PO4 (aa)+ NaOH B) How many moles of NaOH were needed to reach the equivalence point? C) What is the molarity of the H3PO4 solution?

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter14: Equilibria In Acid-base Solutions

Section: Chapter Questions

Problem 50QAP: Morphine, C17H19O3N, is a weak base (K b =7.4107). Consider its titration with hydrochloric acid. In...

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Follow the directions of Question 64. Consider two beakers: Beaker A has a weak acid(K a=1105). Beaker B has HCI. The volume and molarity of each acid in the beakers are the same. Both acids are to be titrated with a 0.1 M solution of NaOH. (a) Before titration starts (at zero time), the pH of the solution in Beaker A is the pH of the solution in Beaker B. (b) At half-neutralization (halfway to the equivalence point), the pH of the solution in Beaker A the pH of the solution in Beaker B. (c) When each solution has reached its equivalence point, the pH of the solution in Beaker A the pH of the solution in Beaker B. (d) At the equivalence point, the volume of NaOH used to titrate HCI in Beaker B the volume of NaOH used to titrate the weak acid in Beaker A.
Consider the titration curve in Exercise 115 for the titration of Na2Cr3 with HCl. a. If a mixture of NaHCO3 and Na2CO3 was titrated, what would be the relative sizes of V1, and V2? b. If a mixture of NaOH and Na2CO3 was titrated, what would be the relative sizes of V1 and V2? c. A sample contains a mixture of NaHCO3 and Na2CO3. When this sample was titrated with 0.100 M HCl, it took 18.9 mL to reach the first stoichiometric point and an additional 36.7 mL to reach the second stoichiometric point. What is the composition in mass percent of the sample?
A bottle of concentrated hydroiodic acid is 57% HI by weight and has a density of 1.70 g/mL. A solution of this strong and corrosive acid is made by adding exactly 10.0 mL to some water and diluting to 250.0 mL. If the information on the label is correct, what volume of 0.988 M NaOH is needed to neutralize the HI solution? Suggest an indicator for the titration.
A 2.500-g sample of a mixture of sodium carbonate and sodium chloride is dissolved in 25.00 mL of 0.798 M HCl. Some acid remains after the treatment of the sample. a Write the net ionic equation for the complete reaction of sodium carbonate with hydrochloric acid b If 28.7 mL of 0.108 M NaOH were required to titrate the excess hydrochloric acid, how many moles of sodium carbonate were present in the original sample? c What is the percent composition of the original sample?
A monoprotic organic acid that has a molar mass of 176.1 g/mol is synthesized. Unfortunately, the acid produced is not completely pure. In addition, it is not soluble in water. A chemist weighs a 1.8451-g sample of the impure acid and adds it to 100.0 mL of 0.1050 M NaOH. The acid is soluble in the NaOH solution and reacts to consume most of the NaOH. The amount of excess NaOH is determined by titration: It takes 3.28 mL of 0.0970 M HCl to neutralize the excess NaOH. What is the purity of the original acid, in percent?
Morphine, C17H19O3N, is a weak base (K b =7.4107). Consider its titration with hydrochloric acid. In the titration, 50.0 mL of a 0.1500 M solution of morphine is titrated with 0.1045 M HCl. (a) Write a balanced net ionic equation for the reaction that takes place during titration. (b) What are the species present at the equivalence point? (c) What volume of hydrochloric acid is required to reach the equivalence point? (d) What is the pH of the solution before any HCl is added? (e) What is the pH of the solution halfway to the equivalence point? (f) What is the pH of the solution at the equivalence point?
A 5.36-g sample of NH4Cl was added to 25.0 mL of 1.00 M NaOH and the resulting solution diluted to 0.100 L.. (a) What is the pH of this buffer solution?. (b) Is the solution acidic or basic?. (c) What is the pH of a solution that results when 3.00 mL of 0.034 M HCl is added to the solution?
Isocyanic acid (HNCO) can be prepared by heating sodium cyanate in the presence of solid oxalic acid according to the equation 2NaOCN(s)+H2C2O4(s)2HNCO(l)+Na2C2O4(s) Upon isolating pure HNCO(l), an aqueous solution of HNCO can be prepared by dissolving the liquid HNCO in water. What is the pH of a l00.-mL solution of HNCO prepared from the reaction of 10.0 g each of NaOCN and H2C2O4, assuming all of the HNCO produced is dissolved in solution? (Ka of HNCO = 1.2 l04.)
You have a solution of the weak acid HA and add some HCl to it. What are the major species in the solution? What do you need to know to calculate the pH of the solution, and how would you use this information? How does the pH of the solution of just the HA compare with that of the final mixture? Explain.
Consider the nanoscale-level representations for Question 111 of the titration of the aqueous strong acid HA with aqueous NaOH, the titrant. Water molecules and Na+ ions are omitted for clarity. Which diagram corresponds to the situation: (a) After a very small volume of titrant has been added to the initial HA solution? (b) Halfway to the equivalence point? (c) When enough titrant has been added to take the solution just past the equivalence point? (d) At the equivalence point? Nanoscale representations for Question 111.
A buffer is prepared in which the ratio [ H2PO4 ]/[ HPO42 ]is 3.0. (a) What is the pH of this buffer? (b) Enough strong acid is added to convert 15% of HPO42- to H2PO4-. What is the pH of the resulting solution? (c) Enough strong base is added to make the pH 7.00. What is the ratio of [H2PO4-] to [HPO42-] at this point?
What will be the pH of a buffer solution prepared from 0.20 mol NH3, 0.40 mol NH4NO3, and just enough water to give 1.00 L of solution?