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- 2. Identify the major product in each of the following reactions: (a) НА OH (b) НА OH (c) CH,CH,NH, (d) HCN H. (e) KMNO, H*Which of the following compounds is the major product of the reaction sequenc shown below? (1) Na CNCH3CN Br (A) (B) NH2 (2) H* H20, A он (C) (D) HO. O Compound C )Compound A Compound D )Compound BWhat is the major product of the reaction sequence below? (A) HOH (B) (1) Na CECH /THE Br (2) HgSO4, H2SO4 H2O (C) (D) OH Compound A Compound C OCompound D
- Which compound will be a major product of the reaction sequence shown below? CH (1) HNO, /H,SO,/ 0 deg C (2) AICI,, OCI (a) (b) CHy (c) -CH (d)10) What is the major product? (A) (C) OH (B) H₂SO4 (cat) H₂O (D) НО. ОН .Which of the following are the major deuterated products of the reaction below? (1) B,De. diglyme D 情 (2) H02, NAOH/H,0 HO, HO. HO. (A) (B) (C) (D) OCompounds A and D Compounds A and B O Compounds A and C Compounds B and D
- If anhydrides react like acid chlorides with the nucleophiles, draw the products formed when each of the following nucleophiles reacts with benzoic anhydride [(C6H5CO)2O]: (a) CH3MgBr (2 equiv), then H2O; (b) LiAlH4, then H2O; (c) LiAlH[OC(CH3)3]3, then H2O.Which is the major product of the reaction below? (1) Na EtO /EIOH (2) dil H*, H-O (A) (B) H2COO OCH3 (C) OCH3 (D) OCH3 Compound A Compound D Compound C Compound B(11) A OB C D A solution of which of the following alkyl halides in methanol will be optically active to begin but slowly lose most or all of its optical activity when heated? H H Br H3CBr Br (B) (A) T Br (C) (D)
- 7В. (2 Draw the structure of the product, substrate or condition in the following reactions (should clearly indicate the stereochemistry). (а) OH (b) OsO vaHSO3 (c) 1) (sia)2 BH 2) NaOH/H,O2 H20 (d) HBr (2 equiv) Br, Br Hint: This is the only product formed (e) Br Br2 H20 OH (f)4. What product is expected from this reaction? (A) (C) N. NH₂ OH -NHNH2 NHANH2 (B) (D) NH NH₂ f NH₂What reagents would you use to carry out the following reaction? (A) H₂ / Pt (B) (C) (D) H₂/Lindlar's ??? Li, EtNH₂ followed by NH4Cl H₂O₂ / NaOH