3. For a van der Waals gas, m show that Z= a V-b RTV, m m 1 (b) Using the Taylor series -≈ 1+x_when_x «1, express the first term of Z in Taylor series in 1-x a RT the limit of V»>b_to obtain Z=1+ b¬ (1/Vm) (Hint: cast the first term into m then do the Taylor series expansion.) 1 1-b/V, ✔ m

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Chapter1: Chemical Foundations
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3. For a van der Waals gas,
V.
show that Z=-
a
m
Vm-b RTVm
1
1-x
(b) Using the Taylor series
the limit of V»b to obtain Z=1+b-
m
then do the Taylor series expansion.)
-≈1+x_when x«1, express the first term of Z in Taylor series in
1
(1/Vm) (Hint: cast the first term into
1-b/V,
a
RT
m
Transcribed Image Text:3. For a van der Waals gas, V. show that Z=- a m Vm-b RTVm 1 1-x (b) Using the Taylor series the limit of V»b to obtain Z=1+b- m then do the Taylor series expansion.) -≈1+x_when x«1, express the first term of Z in Taylor series in 1 (1/Vm) (Hint: cast the first term into 1-b/V, a RT m
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