3. Predict the direction of the following equilibrium shifts (Please label Forward (F) or Reverse (R)):   a) H2O (g) + CO(g)↔ H2(g) + CO2(g) Water is removed? ___ Hydrogen is added? ___ Carbon monoxide is added? ___ b) 4Fe(s) + 3O2(g) ↔ 2Fe2O3(s) + 1648 kJ The temperature is increased? ___ The pressure is increased? ___ c) CaCl2(aq) ↔ Ca2+(aq) + 2Cl-(aq) NaCl is added? ___ AgNO3 is added? ___

Chemistry for Engineering Students
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ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter12: Chemical Equilibrium
Section: Chapter Questions
Problem 12.66PAE
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Hi, I only need help with question # 3. 

 

Equilibrium

  1. Write the equilibrium expressions for the following reactions:
    a) 3Fe(s) + 4H2O(g) ↔ Fe3O4(s) + 4H2(g)
    b) CH3COOH(aq) + H2O(l) ↔ CH3COO-(aq) + H3O+(aq)
    c) N2(g) + 3Br2(g) ↔ 2NBr3(s)
    d) CaCl2(s) ↔ Ca2+(aq) + 2Cl-(aq)


  2. Consider the following equilibrium: 

CH3COOH(l) + C2H5OH(l) ↔ CH3CO2C2H5(l) + H2O(l) Keq =2.2

What must the concentration of water be for a mixture with [CH3COOH]= 0.10M, [CH3CO2C2H5]=2.0M, [C2H5OH]= 5.0M to be at equilibrium? Note: water is NOT the solvent in this reaction, therefore it will be included in the equilibrium expression.

 

 

3. Predict the direction of the following equilibrium shifts (Please label Forward (F) or Reverse (R)):

 

a) H2O (g) + CO(g)↔ H2(g) + CO2(g)

Water is removed? ___
Hydrogen is added? ___
Carbon monoxide is added? ___

b) 4Fe(s) + 3O2(g) ↔ 2Fe2O3(s) + 1648 kJ

The temperature is increased? ___
The pressure is increased? ___

c) CaCl2(aq) ↔ Ca2+(aq) + 2Cl-(aq)


NaCl is added? ___
AgNO3 is added? ___

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