4. Fill in the table 1 2 3 4 5 6 7 8 CH3-CH2-C-CH2-CH2-CH2-CH2-CH3 Proton Chemical Shift (8) in ppm Carbon Chemical Shift (5) in ppm

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
ChapterL3: Carbon (13c) Nmr Spectroscopy
Section: Chapter Questions
Problem 9CTQ
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Ми
H-H COSY Spectrum
(400 MHz, CD, solution)
H
SE
مة اللهو واللعب
ppm
-0.8
1.0
1.2
1.4
-1.6
1.8
-2.0
11
-2.2
2.2
2.0
1.8
1.6
1.4
1.2
1.0
0.8
ppm
H-C me-HSQC Spectrum
(400 MHz, CD, solution)
ppm
10
10
15
20
25
30
35
40
Black cross-peaks CH and CH
Red cross-peaks CH₂
-210
215
2.2
2.0
1.8
1.6
1.4
1.2
1.0
0.8
ppm
Transcribed Image Text:Ми H-H COSY Spectrum (400 MHz, CD, solution) H SE مة اللهو واللعب ppm -0.8 1.0 1.2 1.4 -1.6 1.8 -2.0 11 -2.2 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 ppm H-C me-HSQC Spectrum (400 MHz, CD, solution) ppm 10 10 15 20 25 30 35 40 Black cross-peaks CH and CH Red cross-peaks CH₂ -210 215 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 ppm
4. Fill in the table
1
2
345
6
7
8
CH3-CH2-C-CH2-CH2-CH2-CH2-CH3
Proton
Chemical Shift (d) in ppm
Carbon
Chemical Shift (5) in ppm
H1
C1
H2
C2
C3
H4
C4
H5
C5
H6
C6
H7
C7
H8
C8
1H NMR Spectrum
(400 MHz, CD, solution)
2.4
2.2
2.0
1.8
1.6
1.4
1.2
1.0
0.8
ppm
13C NMR Spectrum
(100 MHz, CD solution)
proton decoupled
solvent
200
180
160
140 120 100 80
60
60
60
40
40
TMS
20 ppm
Transcribed Image Text:4. Fill in the table 1 2 345 6 7 8 CH3-CH2-C-CH2-CH2-CH2-CH2-CH3 Proton Chemical Shift (d) in ppm Carbon Chemical Shift (5) in ppm H1 C1 H2 C2 C3 H4 C4 H5 C5 H6 C6 H7 C7 H8 C8 1H NMR Spectrum (400 MHz, CD, solution) 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 ppm 13C NMR Spectrum (100 MHz, CD solution) proton decoupled solvent 200 180 160 140 120 100 80 60 60 60 40 40 TMS 20 ppm
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