4.00E-04 3.50E-04 3.00E-04 2.50E-04 2.00E-04 1.50E-04 1.00E-04 0.01 0.02 0.03 0.04 0.05 0.06 [DER], M Figure A. Rate of the reaction with increasing DER concentration while AlIR and BEN concentrations are constant. 1. What is the order of reaction with respect to DER? 2. Calculate for the concentration of AIR after mixing for Runs 2 (x) and 3 (y). Run 2 : Run 3: 3. Determine the order of the reaction with respect to AIR. Round off the answer to the nearest whole number. 4. Determine the order of the reaction with respect to BEN. Round off the answer to the nearest whole number. 5. Determine the average rate constant. 6. Write the rate law for the reaction. Rate of Reaction, M/s

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter13: Chemical Kinetics
Section: Chapter Questions
Problem 13.86QE
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4.00E-04
3.50E-04
3.00E-04
2.50E-04
2.00E-04
1.50E-04
1.00E-04
0.01
0.02
0.03
0.04
0.05
0.06
[DER], M
Figure A. Rate of the reaction with increasing DER concentration while AIR and BEN concentrations are
constant.
1. What is the order of reaction with respect to DER?
2. Calculate for the concentration of AIR after mixing for Runs 2 (x) and 3 (y). Run 2 :
Run
3:
3. Determine the order of the reaction with respect to AIR. Round off the answer to the nearest whole
number.
4. Determine the order of the reaction with respect to BEN. Round off the answer to the nearest whole
number.
5. Determine the average rate constant.
6. Write the rate law for the reaction.
Rate of Reaction, M/s
Transcribed Image Text:4.00E-04 3.50E-04 3.00E-04 2.50E-04 2.00E-04 1.50E-04 1.00E-04 0.01 0.02 0.03 0.04 0.05 0.06 [DER], M Figure A. Rate of the reaction with increasing DER concentration while AIR and BEN concentrations are constant. 1. What is the order of reaction with respect to DER? 2. Calculate for the concentration of AIR after mixing for Runs 2 (x) and 3 (y). Run 2 : Run 3: 3. Determine the order of the reaction with respect to AIR. Round off the answer to the nearest whole number. 4. Determine the order of the reaction with respect to BEN. Round off the answer to the nearest whole number. 5. Determine the average rate constant. 6. Write the rate law for the reaction. Rate of Reaction, M/s
CHEMICAL KINETICS
AVATAR reaction shown below was subjected to method of initial rates to determine its rate constant.
AIR + BEN + DER → AANG
The data on the preparation of AANG and the results of the experiment are presented below.
Table 1. Data on the preparation of AANG.
Run 0.375 M of AIR 0.06 M of BEN 1 M of DER dH2O
|1
4.0 mL
2.50 mL
0.25 mL
8.25 mL
2
4.0 mL
10.00 mL
0.25 mL
0.75 mL
3
8.0 mL
2.50 mL
0.25 mL
4.25 mL
Table 2. Data on the determination of rate constant of the formation of AANG at 28°C.
Run Concentration of AIR, M Concentration of BEN, M Concentration of DER, M Rate of reaction, M/s
1
0.10
0.010
0.010
2.4 x 10-4
2
0.040
0.010
9.6 x 10-4
3
0.010
0.010
7.2 x 10-4
4.00E-04
Transcribed Image Text:CHEMICAL KINETICS AVATAR reaction shown below was subjected to method of initial rates to determine its rate constant. AIR + BEN + DER → AANG The data on the preparation of AANG and the results of the experiment are presented below. Table 1. Data on the preparation of AANG. Run 0.375 M of AIR 0.06 M of BEN 1 M of DER dH2O |1 4.0 mL 2.50 mL 0.25 mL 8.25 mL 2 4.0 mL 10.00 mL 0.25 mL 0.75 mL 3 8.0 mL 2.50 mL 0.25 mL 4.25 mL Table 2. Data on the determination of rate constant of the formation of AANG at 28°C. Run Concentration of AIR, M Concentration of BEN, M Concentration of DER, M Rate of reaction, M/s 1 0.10 0.010 0.010 2.4 x 10-4 2 0.040 0.010 9.6 x 10-4 3 0.010 0.010 7.2 x 10-4 4.00E-04
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