5) The volume of several aqueous copper sulfate (CuSO4) solutions was precisely measured at SATP. All of the solutions were made by adding copper sulfate to 100.00 g of water. ncopper sulfate (mol) Vsolution (mL) 0 100.18 0.0330 100.16 0.0696 100.36 0.111 100.81 0.156 101.62 First, estimate the concentration-dependent partial molar volume of copper sulfate in water by taking finite differences. Second, fit the data to a hyperbola and take a derivative of the hyperbola to accurately calculate the partial molar volume of copper sulfate in water at each concentration. Interpret the partial molar volume at infinite dilution - what must copper sulfate be doing to the nearby water molecules?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Question
5)
The volume of several aqueous copper sulfate (CuSO4) solutions was precisely measured
at SATP. All of the solutions were made by adding copper sulfate to 100.00 g of water.
ncopper sulfate (mol)
Vsolution (mL)
0
100.18
0.0330
100.16
0.0696
100.36
0.111
100.81
0.156
101.62
First, estimate the concentration-dependent partial molar volume of copper sulfate in
water by taking finite differences. Second, fit the data to a hyperbola and take a
derivative of the hyperbola to accurately calculate the partial molar volume of copper
sulfate in water at each concentration. Interpret the partial molar volume at infinite
dilution - what must copper sulfate be doing to the nearby water molecules?
Transcribed Image Text:5) The volume of several aqueous copper sulfate (CuSO4) solutions was precisely measured at SATP. All of the solutions were made by adding copper sulfate to 100.00 g of water. ncopper sulfate (mol) Vsolution (mL) 0 100.18 0.0330 100.16 0.0696 100.36 0.111 100.81 0.156 101.62 First, estimate the concentration-dependent partial molar volume of copper sulfate in water by taking finite differences. Second, fit the data to a hyperbola and take a derivative of the hyperbola to accurately calculate the partial molar volume of copper sulfate in water at each concentration. Interpret the partial molar volume at infinite dilution - what must copper sulfate be doing to the nearby water molecules?
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