5. Complete, show the mechanism. Are any other products possible? If yes, show them tebA-2i5 NaOH,H20, heat no boes

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter23: Carbonyl Condensation Reactions
Section23.SE: Something Extra
Problem 28MP
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5. Complete, show the mechanism. Are any other products possible? If yes, show them
awala sO
eenoi
NaOH,H2O, heat
+
HOO
(b)
Is there a way to avoid multiple products (see problem 5), without making structural changes?
en enesned pnitictnoo ton ein
6 Show how to synthetize the following target:
(a)
(6)
Show the mechanism (see problem 7)
Transcribed Image Text:5. Complete, show the mechanism. Are any other products possible? If yes, show them awala sO eenoi NaOH,H2O, heat + HOO (b) Is there a way to avoid multiple products (see problem 5), without making structural changes? en enesned pnitictnoo ton ein 6 Show how to synthetize the following target: (a) (6) Show the mechanism (see problem 7)
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Aldol condensation occurs in aldehydes having α-hydrogen with a dilute base to give β-hydroxy aldehydes called aldols. This reaction is most commonly known as aldol condensation. If the condensation reaction occurs between two different carbonyl compounds it is called crossed aldol condensation.

Aldol Condensation can be defined as an organic reaction in which enolate ion reacts with a carbonyl compound to form β-hydroxy ketone or β-hydroxy aldehyde, followed by dehydration to give a conjugated enone. Aldol Condensation plays a vital role in organic synthesis, creating a path to form carbon-carbon bonds.

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