6. (20 points) Complete the following reactions. No reaction is a possible answer. a) Br 1) CO2 Mg 2) H+, Hао ČH3 b) (CH3)2CULI CH3 c) diethylamine CH.
Q: OH dil. H,SO, (with hydride shift)
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Q: Williamson Syntesis
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Q: 3. Rank the rings below from most activated to least activated.
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Q: A-AgNO3 B-BaCl2 C-CuSO4 D-HCl E-H2SO4 F-NaI G-NaBr H-NaOH I-(NH4)2SO4 J-NH4Cl Explain your answer
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Q: True or False: a. CBr, is more v b. CBr, has a hig c. CBr, has weak d. CBr, has a hig с.
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A: (a)
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Q: EtO `OEt NazCO3
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Q: OH
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Q: NBS DMSO, H2O
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Q: ng is most reactive under E2 conditions? Br Br Br Br (A) (B) (C) (D) Compound B Compound C Compound…
A: Applying condition of E2 elimination reaction.
Q: What is the % of H2O if 102g H2) is produced from 14.6g H2 and excess O2?
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Q: Label the equivalent hydrogens
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Q: H. i Draw the missing curved arrow notation. H. H. OF 25 OLIESTIONS COMBLETED
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- (5 points) What hydrolysis products are formed when the following compound is treated with aqueous acid? No reaction is an acceptable answer. CH3 H3C- H20, H+Electrostatic potential maps of anisole and thioanisole are shown. Which do you think is the stronger acid, p-methoxybenzoic acid or p-(methylthio)benzoic acid? Explain.3. (15 points) Complete the reaction scheme below. Show all reagents and intermediates. No reaction is a possible answer. H20 a) H20 LIAIH4 b) H3O*
- Rank the following in order of increasing basicity. соо coo" coo .coo7. For each of the following pairs of species, encircle the stronger nucleophile in acetone? (a) H3C-OH or H,C- (b). H3C- or H,C-OH2 (c) H3C-OH or H3C-NH2 (d) o (e) () or or or NH (h) CH,S CH;Se or or NH PH (1) CH,Se or BrQuestion 5. (20 points) Consider the following reaction. + PhLi (2 eq.) then water a) Propose a structure for the final product. b) Give a complete mechanism for the transformation. c) Draw an energy diagram of the transformation and briefly comment on the relative energies of the starting material, final product, and any intermediate(s), and about the rate determining step.
- e) Circle the most basic nitrogen atom in the compound below. -NH2 ) The following isomeization reaction occurs at room temperature. Draw a stepwise mechanism for the reaction and explain why it occurs. OH H,SO, (R)- Carvone CarvacrolPredict the major product of the given reaction and then draw a reasonable mechanism for the product formation using appropriate curved arrow notation. Part 1: OH H2SO4 (aq) view structure Part 2 out of 4 H,0 H,SO4 HSO, HO finish structure . draw structure . H;O*please answer no. 1-4 :)
- (7) Rank the following nucleophiles in order of their reactivity in an SN2 reaction (1 - most reactive.4 - least reactive). REMEMBER: The SN2 reaction has a crowded transition state! H,C-oProvide a curved arrow mechanism for the SN1 reaction below: CI CH3 H,C NACNOrganic Chemistry Loudon | Parise SEVENTH EDITION Draw the major organic product for each of the two situations. (a) Phenylacetic acid is treated first with Br₂ and one equivalent of PBr3, then with a large excess of ethanol. Be on Incorrect (b) Propionic acid is treated first with Br, and one equivalent of PBr3, then with a large excess of ammonia. presented by Macmillan Leaming Br f NH,