7) Assign partial charges on the CI-CI (polarized) below. This reaction proceeds through a three-membered ring halonium intermediate. The first step involves arrows similar to the carbene reaction above plus an additional arrow showing the Cl-Cl bond breaking. The second step is SN2 at the more substituted carbon. 8) Complete the following reaction by adding curved arrows, intermediates, and the expected products. S :CI-CI: :CI: 9) Label the Mechanistic steps above and the halonium ion intermediate. Because the second step is similar to SN2 the halides add anti to each other.
7) Assign partial charges on the CI-CI (polarized) below. This reaction proceeds through a three-membered ring halonium intermediate. The first step involves arrows similar to the carbene reaction above plus an additional arrow showing the Cl-Cl bond breaking. The second step is SN2 at the more substituted carbon. 8) Complete the following reaction by adding curved arrows, intermediates, and the expected products. S :CI-CI: :CI: 9) Label the Mechanistic steps above and the halonium ion intermediate. Because the second step is similar to SN2 the halides add anti to each other.
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter24: Carboxylic Acids & Derivatives
Section: Chapter Questions
Problem 12CTQ
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