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- 2. Predict the mechanism and the mechanism the following reaction. H2SO4 CH3OH2. Determine the structures of the four products (two sub, two elim) that form in this reaction, and provide a step-wise mechanism for their formation. HINT: Think about what happens with allylic radicals! CI CH3OH 4 products total2. Provide the mechanism for the reaction illustrated below. Show the relevant intermediate/transition state. Br N2OH
- 3. Show a plausible mechanism for the reaction below. , NH2 ELOH, cat. HCI CH H,C- CH NH, CHConsider the reaction below. Predict which mechanism type will be most likely to occur. | CH3OH Question 39 of 46 Br A) SN1 B) E1In an E2 mediated elimination reaction of an alkyl halide (H-X) using NaOCH3 as base, which of the following statement is not true? O The reactivity order for alkyl halides (RX) is tertiary secondary> primary. O The rate of reaction = k2 (alkyl halide] [NaOCH₂] O The reaction occurs in a single step. O The rate is independent of the leaving group.
- Provide a plausible arrow pushing mechanism for the reaction below. Os-OtBu 's-OtBu HN 1. LDA 2. OMe SO,Ph 3. aqueous workupQ10. For each of the following reactions (a-b), predict whether the substitution is more likely to occur following an Sn1 or Sn2 mechanism; explain your reasoning. Draw the products of each nucleophilic substitution paying particular attention to the stereochemistry of carbon 1. a) Br, CH3 MeOH H3C b) Br NaOH 1 DMF* H3C *N,N-dimethylformamideOH 4. Propose a mechanism for the alkylation step in Question ii) and iii) above Show all steps with structures.
- 4. Please write out the general mechanism for the electrophilic addition to alkene. (two steps mechanisum, E+: electrophile, Nuc: nucleophile)Suggest a reasonable mechanism for the reaction shown Br here. HO CH;CH,OHIn each case tell which SN2 reaction will proceed faster.1. The displacement by I- on (a) CH3Cl or (b) CH3OTos. Select A or B2. The displacement by OH- on (a) CH3Br or (b) CH3I. Select A or B