874 Problem 12 of 20 Submit Draw the structure of the reactant needed to complete the Sonogashira coupling shown below. + Select to Draw Pd(PPh3)2Cl2, CuI EtзN થ 874 Problem 12 of 20 Submit Select to Draw S Pd(PPh3)2Cl2, CUI EtзN ☑ Version: 3.133.20 + 4998 production
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- Show how the synthetic scheme developed in Problem 23.67 can be modified to synthesize this triiodobenzoic acid X-ray contrast agent.Nitriles, R–=C≡N, undergo a hydrolysis reaction when heated with aqueous acid. What is the structure of the compound produced by hydrolysis of propanenitrile, CH3CH2C≡N, if it has IR absorptions from 2500–3100 cm-1 and at 1710 cm-1, and has M+=74?Draw a resonance structure of the acetonitrile anion, -: CH2CN, and account for the acidity of nitriles.
- Cembrene, C20H32, is a diterpenoid hydrocarbon isolated from pine resin. Cembrene has a UV absorption at 245 nm, but dihydrocembrene (C20H34), the product of hydrogenation with 1 equivalent of H2, has no UV absorption. On exhaustive hydrogenation, 4 equivalents of H2 react, and octahydrocembrene, C20H40, is produced. On ozonolysis of cembrene, followed by treatment of the ozonide with zinc, four carbonylcontaining products are obtained: Propose a structure for cembrene that is consistent with its formation from geranylgeranyl diphosphate.My C mentProblemID=192850292 A&P II Mast o ethyl butanoate ▼ PSY Connect Part A Pears Bb 1574 b Ansv G great H₂C NN Course Home pt My [ chem in career H 12D EXP CONT Predict the major organic product formed when the compound shown below undergoes a reaction with LiAlH4. Interactive 3D display mode CH3 Chen Chen Draw the molecule on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Ter * I ο phys G phys N OIdentify the major prouct of the folowing sololvsi reaction of 3bromo-1-methyiycopentene with methanol, Br CH,OH to
- What is the expected major product for the following reaction sequence? OH OH + enantiometr 01 00 0 || OIV OV OsO4 (cat.) NMO 애 OH + enantiomer 11 OH + enantiomer ||| IV مة HO OHThe following nucleophilic substitution occurs with rearrangement. Suggest a mecha- nism for formation of the observed product. If the starting material has the S configura- tion, what is the configuration of the stereocenter in the product? NaOH OH H,0N-Nitrosamines by themselves are not significant carcinogens. However, they are activated in the liver by a class of iron-containing enzymes (members of the cytochrome P-450 family). Activation involves the oxidation of a C-H bond next to the amine nitrogen to a C-OH group. OH ОН N=0 N=O Og 'N- H+ H N,+ cyt P-450 N-Nitroso- 2-Нydroxy-N- nitrosopiperidine An alkyl diazonium ion piperidine (a carcinogen) Show how this hydroxylation product can be transformed into an alkyl diazonium ion, an active alkylating agent and therefore a carcinogen, in the presence of an acid catalyst.
- What is the best description of the product distribution from the reaction shown (- OTF=triflate, trifluoromethanesulfonate) Na OH,coo CH, COOHH,0 C D. DA mixture of compounds B and D OA mixture of compounds A and C OA mixture of compounds A and B OA mixture of compounds A and DDetermine product (A) of the reaction (1) NK + DMF CH2 – Br (A) (81%) (2) HO¯/H2O (Benzyl bromide) (a) Ph – NH2 (c) Ph – CH2 – NH – CO,H (b) Ph – CH2 – NH2 (d) Ph – CH, - NH – CHOH₂C ཏཱཏི 1 ནི OH 1. Br2, PBг3 2. H₂O H3C OH Br The a-bromination of carbonyl compounds by Br2 in acetic acid is limited to aldehydes and ketones because acids, esters, and amides don't enolize to a sufficient extent. Carboxylic acids, however, can be a-brominated by first converting the carboxylic acid to an acid bromide by treatment with PBr3. Following enolization of the acid bromide, Br2 reacts in an a-substitution reaction. Hydrolysis of the acid bromide completes the reaction. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions :0: H3C Br Br + :::OH2 Br H₂O H3C Br за