A 0.5745 g sample of an alloy containing principally bismuth and lead is dissolved in nitric acid and diluted to 250.0 mL in a volumetric flask. A 50.00 mL aliquot is withdrawn, the pH adjusted to 1.5, and the bismuth titrated with 30.26 mL of 0.01024 M EDTA . The pH of the solution is then increased to 5.0 and the lead titrated with 20.42 mL of the same EDTA solution. Calculate the nerrentages of lead and bismuth in the alloy.

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter16: Reactions Between Acids And Bases
Section: Chapter Questions
Problem 16.59QE
icon
Related questions
Question
2
A 0.5745 g sample of an alloy containing principally bismuth and lead is dissolved in nitric acid and
diluted to 250.0 mL in a volumetric flask. A 50.00 mL aliquot is withdrawn, the pH adjusted to 1.5,
and the bismuth titrated with 30.26 mL of 0.01024 M EDTA. The pH of the solution is then
increased to 5.0 and the lead titrated with 20.42 mL of the same EDTA solution. Calculate the
percentages of lead and bismuth in the alloy.
Transcribed Image Text:A 0.5745 g sample of an alloy containing principally bismuth and lead is dissolved in nitric acid and diluted to 250.0 mL in a volumetric flask. A 50.00 mL aliquot is withdrawn, the pH adjusted to 1.5, and the bismuth titrated with 30.26 mL of 0.01024 M EDTA. The pH of the solution is then increased to 5.0 and the lead titrated with 20.42 mL of the same EDTA solution. Calculate the percentages of lead and bismuth in the alloy.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Knowledge Booster
Basics of Titrimetric Analysis
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry: Principles and Practice
Chemistry: Principles and Practice
Chemistry
ISBN:
9780534420123
Author:
Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781133949640
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning