Assume that the total volume of a metal sample is the sumof the volume occupied by the metal ions making up the lattice andthe (separate) volume occupied by the conduction electrons. Thedensity and molar mass of sodium (a metal) are 971 kg/m3 and 23.0g/mol, respectively; assume the radius of the Na+ ion is 98.0 pm. (a)What percent of the volume of a sample of metallic sodium is occupiedby its conduction electrons? (b) Carry out the same calculationfor copper, which has density, molar mass, and ionic radius of8960 kg/m3, 63.5 g/mol, and 135 pm, respectively. (c) For which ofthese metals do you think the conduction electrons behave morelike a free-electron gas?

College Physics
11th Edition
ISBN:9781305952300
Author:Raymond A. Serway, Chris Vuille
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Chapter1: Units, Trigonometry. And Vectors
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Assume that the total volume of a metal sample is the sum
of the volume occupied by the metal ions making up the lattice and
the (separate) volume occupied by the conduction electrons. The
density and molar mass of sodium (a metal) are 971 kg/m3 and 23.0
g/mol, respectively; assume the radius of the Na+ ion is 98.0 pm. (a)
What percent of the volume of a sample of metallic sodium is occupied
by its conduction electrons? (b) Carry out the same calculation
for copper, which has density, molar mass, and ionic radius of
8960 kg/m3, 63.5 g/mol, and 135 pm, respectively. (c) For which of
these metals do you think the conduction electrons behave more
like a free-electron gas?

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