B AG = 18.3 kJ/mol AG = 5.9 kJ/m. %3D ion

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter17: Chemcial Thermodynamics
Section: Chapter Questions
Problem 17.75QE
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The energy difference between a tert-butyl group going from equatorial to axial in a cyclohexane is 18.3 kJ/mol. When two of the carbon atoms are replaced with oxygen atoms (molecule B) the energy difference between the two chair conformations drops to 5.9 kJ/mol. Explain this difference. (Hint: Consider what makes putting groups axial unfavorable).

B
AG = 18.3 kJ/mol
AG = 5.9 kJ/m.
%3D
ion
Transcribed Image Text:B AG = 18.3 kJ/mol AG = 5.9 kJ/m. %3D ion
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