Based on the following data for the fırst order reaction J products, calculate the rate constant k (in s-1). Time [J] Os 1.0000 M 900 .5231 3000 .1153 O 2.9 x 10-4 Ο 1.4 x 103 O 5.3 x 10-4 O 1.0 x 10-3 O 7.2 x 10-4

Chemistry by OpenStax (2015-05-04)
1st Edition
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Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Chapter12: Kinetics
Section: Chapter Questions
Problem 31E: The following data have been determined for the reaction: I+OCIIO+CI 1 2 3 [I] 0.10 0.20 0.30 [OCI]...
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Based on the following data for the
fırst order reaction J
products, calculate
the rate constant k (in s1).
Time
[J]
Os
1.0000 M
900
.5231
3000
.1153
O 2.9 x 104
O 1.4 x 103
O 5.3 x 10-4
О 1.0 х 10-3
O 7.2 x 10-4
Transcribed Image Text:Based on the following data for the fırst order reaction J products, calculate the rate constant k (in s1). Time [J] Os 1.0000 M 900 .5231 3000 .1153 O 2.9 x 104 O 1.4 x 103 O 5.3 x 10-4 О 1.0 х 10-3 O 7.2 x 10-4
R = .008314 kJ/K (Gas Constant)
F = 96.485 kJ/(V mol)
[A]
pK, + log
(班)
[base]
pH
pK, + log
OR
pH
%3D
[acid]
[HA]
AG°
AH° - TASº
AG = AG° + RTINQ
AG° = -RT/nKeq
AG° = -nFE°cell
%3D
0591
Ecell
E°cll
logQ
First Order
Radioactivity
Second Order
[Alo
In
Xo
1
kt
In
= kt
= kt +
[A]t
[A]
[A]o
.693
.693
ty =
ty =
ty =
k
k
K[A]
Transcribed Image Text:R = .008314 kJ/K (Gas Constant) F = 96.485 kJ/(V mol) [A] pK, + log (班) [base] pH pK, + log OR pH %3D [acid] [HA] AG° AH° - TASº AG = AG° + RTINQ AG° = -RT/nKeq AG° = -nFE°cell %3D 0591 Ecell E°cll logQ First Order Radioactivity Second Order [Alo In Xo 1 kt In = kt = kt + [A]t [A] [A]o .693 .693 ty = ty = ty = k k K[A]
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