by mass spectrometry! 3. How could the following pairs of isc CH3 CH2-CH2-CH3 (а) and CH3 CH3 CH3 (b) CH3 CH3 CH=CH2 CH3 CH2-CH2 CH3 and CH3 CH3 (c) CH CH3 CH2 and CH3 CH CH3 CH3 CH3

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter14: Mass Spectrometry
Section: Chapter Questions
Problem 14.29P
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3. How could the following pairs of isomeric compounds be differentiated by mass spectrometry
CH-CH2-CH3
CH3
(a)
and
CH3
CH3
H.
CH3
(b)
CH3
CH=CH2
CH3
CH3
CH2-CH2
CH3
and
CH3
H
(c)
CH3
CH2
CH
CH3
CH
CH3
and
CH3
CH2
CH3
CH3
Transcribed Image Text:3. How could the following pairs of isomeric compounds be differentiated by mass spectrometry CH-CH2-CH3 CH3 (a) and CH3 CH3 H. CH3 (b) CH3 CH=CH2 CH3 CH3 CH2-CH2 CH3 and CH3 H (c) CH3 CH2 CH CH3 CH CH3 and CH3 CH2 CH3 CH3
(d)
CH3
CH3-CH2-CH,-CH-CH3
and
CH3-C-CH2-CH3
(e)
CH3-CH2-CH2-CH2-CH2-Br
and
CH3-CH2-CH-CH2-CH3
Br
(f)
CH3-CH-CH2-Ĉ
0-
CH3
CH3-CH2-CH2-C
-0-CH2-CH3
and
CH3
(g)
CH3
N.
CH3
N.
CH3-CH2
and
CH3-CH,-CH,
H.
CH3
and
CH3-CH2-CH2-NH-CH3
(h)
CH3-CH2-CH,-CH2-NH2
Lon,
(i)
and
-CH2
-CH3
CH2-CH3
CH3
CH3
(j)
-C-
-CH3
and
CH2-CH-CH3
CH3
Transcribed Image Text:(d) CH3 CH3-CH2-CH,-CH-CH3 and CH3-C-CH2-CH3 (e) CH3-CH2-CH2-CH2-CH2-Br and CH3-CH2-CH-CH2-CH3 Br (f) CH3-CH-CH2-Ĉ 0- CH3 CH3-CH2-CH2-C -0-CH2-CH3 and CH3 (g) CH3 N. CH3 N. CH3-CH2 and CH3-CH,-CH, H. CH3 and CH3-CH2-CH2-NH-CH3 (h) CH3-CH2-CH,-CH2-NH2 Lon, (i) and -CH2 -CH3 CH2-CH3 CH3 CH3 (j) -C- -CH3 and CH2-CH-CH3 CH3
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