Calculate AG and the exponent value (the x of 10) for K, for the following reactions at 25°C: (a) Mg(s) + Pb2 (aq) = Mg²"(aq) + Pb(s) AG":-430.3 x:75 (b) O2(g) + 4H (aq) + 4FE2 (aq) = 2H,0(1) + 4Fe"(aq) AG:-177.5 x:31 (c) 2Al(s) + 31,(8) 2A*(aq) + 61 (aq) AG":-131.2 x: 23

Principles of Modern Chemistry
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Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
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Chapter14: Chemical Equilibrium
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Problem 15P
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Calculate AG and the exponent value (the x of 10) for K, for the following reactions at 25°C:
(a) Mg(s) + Pb2 (aq) Mg2"(aq) + Pb(s)
AG: -430.3
x:75
(b) O2(g) + 4H"(aq) + 4FE2*(aq) = 2H,0(1) + 4Fe*(aq)
AG":-177.5
x:31
(c) 2AI(s) + 31,(8) = 2A1*(aq) + 6I (aq)
AG":-131.2
x: 23
Transcribed Image Text:Calculate AG and the exponent value (the x of 10) for K, for the following reactions at 25°C: (a) Mg(s) + Pb2 (aq) Mg2"(aq) + Pb(s) AG: -430.3 x:75 (b) O2(g) + 4H"(aq) + 4FE2*(aq) = 2H,0(1) + 4Fe*(aq) AG":-177.5 x:31 (c) 2AI(s) + 31,(8) = 2A1*(aq) + 6I (aq) AG":-131.2 x: 23
Standard Reduction Potentiais
in Aqueous Solutions at 25 °C
Reduction
Oxidizing Agent
Reducing Agent
Potential (V)
F2
H,O2
MnO,
2е
2F
2.87
2H* + 2e
2H20
Mn2+ + 4H20
1.78
8H* + 5e¯
1.51
Au3+
3e
Au
1.50
+
Cl2
O2
Cr,0,2- +
Br2
NO3
Ag*
12
+
2e-
1.36
4H+ + 4e
2H20
2Cr3+ + 7H2O
1.23
14H+ + 6e-
1.23
2e
2Br
1.07
NO + 2H20
Ag
+
4H* + 3e
0.96
e
0.80
+
2e
21-
0.54
Cu*
+
e-
Cu
0.52
O2
Cu2+
2H,0 + 4e
2e
2e
+
4OH-
0.40
+
Cu
0.34
2H30* +
Pb2+
Sn2+
H2 + 2H,0
0.00
+
2e
Pb
-0.13
2e
Sn
-0.14
Ni2+
Fe2+
Cro+
Zn2+
2e
Ni
-0.26
+
2e
Fe
-0.45
Зе
Cr
-0.74
Zn
H2 + 20H-
+
2e
-0.76
2H,0
Mn2+
2e
-0.83
2e
Mn
-1.19
A3+
3e
AI
-1.66
Mg²+
Na
Ca2+
Ba2+
+
2e
Mg
-2.37
e
Na
-2.71
2e
2e
Са
-2.87
Ва
-2.91
K*
e
K
-2.93
Li*
e
Li
-3.04
Increasing Strength of Oxidizing Agent
- + + + + +
↑ ↑ ↑ ↑ ↑ ↑ ↑ ↑ ↑
Increasing Strength of Reducing Agent
Transcribed Image Text:Standard Reduction Potentiais in Aqueous Solutions at 25 °C Reduction Oxidizing Agent Reducing Agent Potential (V) F2 H,O2 MnO, 2е 2F 2.87 2H* + 2e 2H20 Mn2+ + 4H20 1.78 8H* + 5e¯ 1.51 Au3+ 3e Au 1.50 + Cl2 O2 Cr,0,2- + Br2 NO3 Ag* 12 + 2e- 1.36 4H+ + 4e 2H20 2Cr3+ + 7H2O 1.23 14H+ + 6e- 1.23 2e 2Br 1.07 NO + 2H20 Ag + 4H* + 3e 0.96 e 0.80 + 2e 21- 0.54 Cu* + e- Cu 0.52 O2 Cu2+ 2H,0 + 4e 2e 2e + 4OH- 0.40 + Cu 0.34 2H30* + Pb2+ Sn2+ H2 + 2H,0 0.00 + 2e Pb -0.13 2e Sn -0.14 Ni2+ Fe2+ Cro+ Zn2+ 2e Ni -0.26 + 2e Fe -0.45 Зе Cr -0.74 Zn H2 + 20H- + 2e -0.76 2H,0 Mn2+ 2e -0.83 2e Mn -1.19 A3+ 3e AI -1.66 Mg²+ Na Ca2+ Ba2+ + 2e Mg -2.37 e Na -2.71 2e 2e Са -2.87 Ва -2.91 K* e K -2.93 Li* e Li -3.04 Increasing Strength of Oxidizing Agent - + + + + + ↑ ↑ ↑ ↑ ↑ ↑ ↑ ↑ ↑ Increasing Strength of Reducing Agent
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