CATION CONFIRMATORY TEST OBSERVATION ADDED REAGENT(S) Excess NH3 KSCN K4Fe(CN)6 K3Fe(CN)6 Na₂C₂04 NaOH (in evaporating dish) ANION CONFIRMATORY TEST OBSERVATION ADDED REAGENT(S) HNO3, Fe(NO3)3 HNO3, KMnO4 (to the ppt) CH3COOH MgCl2 6M H₂SO4, FeSO4, 18M H₂SO4 POSSIBLE ION(S) PRESENT? OBSERVATIONS brown ppt Blood red complex Prussian blue ppt NVR NVR Litmus paper: red to blue OBSERVATIONS Yellow aqueous layer; pink toluene layer Yellow-brown aqueous layer; pink toluene layer N/A NVR NVR
CATION CONFIRMATORY TEST OBSERVATION ADDED REAGENT(S) Excess NH3 KSCN K4Fe(CN)6 K3Fe(CN)6 Na₂C₂04 NaOH (in evaporating dish) ANION CONFIRMATORY TEST OBSERVATION ADDED REAGENT(S) HNO3, Fe(NO3)3 HNO3, KMnO4 (to the ppt) CH3COOH MgCl2 6M H₂SO4, FeSO4, 18M H₂SO4 POSSIBLE ION(S) PRESENT? OBSERVATIONS brown ppt Blood red complex Prussian blue ppt NVR NVR Litmus paper: red to blue OBSERVATIONS Yellow aqueous layer; pink toluene layer Yellow-brown aqueous layer; pink toluene layer N/A NVR NVR
Chapter27: Molecular Fluorescence Spectroscopy
Section: Chapter Questions
Problem 27.9QAP
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