CH3 f RR'CHОН + О-S `CH3 DCC, H* » ?

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter22: Carbonyl Alpha-substitution Reactions
Section22.SE: Something Extra
Problem 26MP: Nonconjugated , -unsaturated ketones, such as 3-cyclohexenone, are in an acid-catalyzed equilibrium...
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with detail mechanism do ii
(b) Write the product(s) and mechanism for
the following reactions:
(1)
(i)
ScO2
→?
aq. 'dioxane
fi) RR'CHOH + O=S
CH3
DCC, H+
→?
`CH3
DDQ
(ii)
→?
C6H6/reflux
Transcribed Image Text:(b) Write the product(s) and mechanism for the following reactions: (1) (i) ScO2 →? aq. 'dioxane fi) RR'CHOH + O=S CH3 DCC, H+ →? `CH3 DDQ (ii) →? C6H6/reflux
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