d. Find AH for the dissolution of 1.00 g NaOH in water. e. Find AH for the dissolution of 1 mole NaOH in water. ΔΗ = ΔΗ = kJ/g kJ/mol f. Given that NaOH exists as Na and OH ions in solution, write the equation for the reaction that occurs when NaOH is dissolved in water.

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter5: Principles Of Chemical Reactivity: Energy And Chemical Reactions
Section: Chapter Questions
Problem 113SCQ
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Can I get help solving question 2 sections d-f. Using the information from the fist page.
Experiment 14
Advance Study Assignment: Heat Effects and Calorimetry
1. A metal sample weighing 147.90 g and at a temperature of 99.5°C was placed in 49.73 g of water in a calo-
rimeter at 23.0°C. At equilibrium the temperature of the water and metal was 41.8°C.
What was Ar for the water? (Art final initial)
41.8°C -230°C
a.
b. What was Ar for the metal?
41.8-99.5
C.
How much heat flowed into the water? (Take the specific heat of the water to be 4.18 J/gºC.)
9 = SH. MAT > (4₁183 184) (49.73.8) (18.88) = 3908
-853383
e. What is the approximate molar mass of the metal? (Use Eq. 4.)
25
2007008
- 11/15°C) 458 45 ) =
MM =
d. Calculate the specific heat of the metal, using Equation 3.
9H₂0 = SH₁₂
•M. At
#20
=-SH₁ Mm Atm
3908 (SH)(147.⁹90) (-5.7.7) = +0.457=+5H (458
C.
b. Calculate 41120, using Equation 1.
90-418-3/5°c) (49.729/26.4%)=5487
Find AH for the reaction as it occurred in the calorimeter (Eq. 5).
AH = -9₂0
9=SH.M.At
M=4989+ 49.72 = 54.79
18,8 °C
-57.7c
2. When 4.98 g of NaOH was dissolved in 49.72 g of water in a calorimeter at 23.7°C, the temperature of the
solution went up to 50.1°C.
a.
Is this dissolution reaction exothermic? Yes
Why?
Because releases neat as its dissolved in water.
This raises the temperature of the Soution.
5.49x3 joules
9=154.79) (418-19) (26.400)
9=6036.3 J
-6036
AH =
391 x10³
joules
joules/g°C
54.6 mot
g/mol
6,04x103
joules
(continued on following page)
Transcribed Image Text:Experiment 14 Advance Study Assignment: Heat Effects and Calorimetry 1. A metal sample weighing 147.90 g and at a temperature of 99.5°C was placed in 49.73 g of water in a calo- rimeter at 23.0°C. At equilibrium the temperature of the water and metal was 41.8°C. What was Ar for the water? (Art final initial) 41.8°C -230°C a. b. What was Ar for the metal? 41.8-99.5 C. How much heat flowed into the water? (Take the specific heat of the water to be 4.18 J/gºC.) 9 = SH. MAT > (4₁183 184) (49.73.8) (18.88) = 3908 -853383 e. What is the approximate molar mass of the metal? (Use Eq. 4.) 25 2007008 - 11/15°C) 458 45 ) = MM = d. Calculate the specific heat of the metal, using Equation 3. 9H₂0 = SH₁₂ •M. At #20 =-SH₁ Mm Atm 3908 (SH)(147.⁹90) (-5.7.7) = +0.457=+5H (458 C. b. Calculate 41120, using Equation 1. 90-418-3/5°c) (49.729/26.4%)=5487 Find AH for the reaction as it occurred in the calorimeter (Eq. 5). AH = -9₂0 9=SH.M.At M=4989+ 49.72 = 54.79 18,8 °C -57.7c 2. When 4.98 g of NaOH was dissolved in 49.72 g of water in a calorimeter at 23.7°C, the temperature of the solution went up to 50.1°C. a. Is this dissolution reaction exothermic? Yes Why? Because releases neat as its dissolved in water. This raises the temperature of the Soution. 5.49x3 joules 9=154.79) (418-19) (26.400) 9=6036.3 J -6036 AH = 391 x10³ joules joules/g°C 54.6 mot g/mol 6,04x103 joules (continued on following page)
106 Experiment 14 Heat Effects and Calorimetry
d. Find AH for the dissolution of 1.00 g NaOH in water.
e.
Find AH for the dissolution of 1 mole NaOH in water.
ΔΗ Ξ
ΔΗ =
kJ/g
kJ/mol
f. Given that NaOH exists as Na and OH ions in solution, write the equation for the reaction that
occurs when NaOH is dissolved in water.
AH =
g. Given the following heats of formation, AH, in kJ per mole, as obtained from a table of AH, data,
calculate AH for the reaction in Part (f). Compare your answer with the result you obtained in Part (e).
NaOH(s), -425.6; Na (aq), -240.1; OH (aq), -230.0
kJ/mol
Transcribed Image Text:106 Experiment 14 Heat Effects and Calorimetry d. Find AH for the dissolution of 1.00 g NaOH in water. e. Find AH for the dissolution of 1 mole NaOH in water. ΔΗ Ξ ΔΗ = kJ/g kJ/mol f. Given that NaOH exists as Na and OH ions in solution, write the equation for the reaction that occurs when NaOH is dissolved in water. AH = g. Given the following heats of formation, AH, in kJ per mole, as obtained from a table of AH, data, calculate AH for the reaction in Part (f). Compare your answer with the result you obtained in Part (e). NaOH(s), -425.6; Na (aq), -240.1; OH (aq), -230.0 kJ/mol
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