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- • Draw the curved arrow mechanism for the following reaction. o Show all electrons, spectator ions, formal charges, and intermediates. o Only account for the products shown. • Account for any stereochemistry and regiochemistry provided. Overall Reaction 1. 1 equiv CH₂MgBr, ether 2 water workup OH + enantiomer2) Predict the major product for each reaction. Indicate correct stereochemistry. a. b. H3C H3C HO ||||| HO ||||| CH3 ||||| Br H Br CH3 H NaOH NaOH thrive qode-tums ng uboiqyPlease fill in the missing reactants, reagents or products in the following reactions. Indicate relative stereochemistry where it is necessary CI j)
- Complete the following: Stereochemistry, enantio-, and regioselectivity are important. CrO3, H2SO4 a) OH Bromination of an alcohol (Sn2) type EtO₂C CO₂Et b) b) d) H3CO type NH2 a) b) H3CO type a) b) OH g) type CN CI h) acetone Swern Oxidation type type CO₂H type Доно i) Me3SICI, Imidazole OSiMe3 Et3N, CH2Cl2 Br type a) Mg°, THF Br j) b); H3O+ H2SO4 (H+) MeOH OMe type typeDraw the organic product of the following reaction. CH3 m-CICgH,CO;H • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If the reaction produces a racemic mixture, just draw one stereoisomer. • If more than one product is possible, only draw the major product. opy asteTReview TOpics] [References Draw a structural formula for the major product of the reaction shown. CH3 CH3CHCH=CH2 Show product steréochemistry IF the reactant alkene has both carbons of the double bond within a • Do not show stereochemistry in other cases. If the reaction produces a racemic mixture, just draw one stereoisomer. C P opy aste C.
- Draw and/ov the major ce Bv product(s) product CH 3 S DMF сызон A котви in the where reactions applicable. below. Specify stereochemistry2. a) b) Ez Draw the products of each / elimination Фоснасня H |||| Br H3 C H Ф OCH₂CH3Rank the compounds in each set from most to least reactive in an EAS reaction
- To preview image Click Here! a. Give the curved arrow-pushing and the Allowed product of the following cycloaddition. State whether the product is achiral, a meso compound, a pure enantiomer or a racemic mixture. H&CO OHC A B CHO heat b. Draw the HOMO for reactant A and the LUMO for reactant B on top of the structures below H₂CO 3 A HOMO OHC B LUMO CHO c. Does the allowed reaction proceed suprafacial/suprafacial or suprafacial/ antarafacialhv > ? Major product *product (Stereochemistry (ii) Minor it st be denicted)A. Give the curved arrow-ppushing & the allowed product of the following cycloaddition. State whether the allowed product is achiral, a meso compound, a pure eantiomer, or a racemic mixture. B. Draw the H/O/M/O for reactant A & the L/U/M/O for reactant B on top of the structures below. C. Does the allowed reaction proceed suprafacial/suprafacial or suprafacial/antarafacial.