Explain the observed stereochemistry. When the second intermediate is redrawn from the following perspective, it becomes clear that

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter4: Organic Compounds: Cycloalkanes And Their Stereochemistry
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Problem 61AP: Ketones react with alcohols to yield products called acetals. Why does the all-cis isomer of...
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Explain the observed stereochemistry.
When the second intermediate is redrawn from the following perspective, it becomes clear that
O the electrons in the carbon-carbon-bond come from above the carbon-oxygen bond, allowing for the chirality
center to be generated with the stereochemistry shown.
O the electrons in the carbon-oxygen-bond come from above the carbon-carbon bond, allowing for the chirality
center to be generated with the stereochemistry shown.
the electrons in the carbon-carbon-bond come from below the carbon-oxygen bond, allowing for the chirality
center to be generated with the stereochemistry shown.
O the electrons in the carbon-oxygen-bond come from below the carbon-carbon bond, allowing for the chirality
center to be generated with the stereochemistry shown.
Transcribed Image Text:Explain the observed stereochemistry. When the second intermediate is redrawn from the following perspective, it becomes clear that O the electrons in the carbon-carbon-bond come from above the carbon-oxygen bond, allowing for the chirality center to be generated with the stereochemistry shown. O the electrons in the carbon-oxygen-bond come from above the carbon-carbon bond, allowing for the chirality center to be generated with the stereochemistry shown. the electrons in the carbon-carbon-bond come from below the carbon-oxygen bond, allowing for the chirality center to be generated with the stereochemistry shown. O the electrons in the carbon-oxygen-bond come from below the carbon-carbon bond, allowing for the chirality center to be generated with the stereochemistry shown.
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