Explain the order of chemical shifts of the carbon atoms in the 13C spectra of cyclohexanone (fig 22.6 ) and adipic acid (fig .22.9) attached below .

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
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Explain the order of chemical shifts of the carbon atoms in the 13C spectra of cyclohexanone (fig 22.6 ) and adipic acid (fig .22.9) attached below .
FIG. 22.6
The 13C NMR spectrum of
cyclohexanone (100 MHz).
3.
3
CDCI,
1
TMS
200
180
160
140
120
100
80
60
40
PPM (8)
Transcribed Image Text:FIG. 22.6 The 13C NMR spectrum of cyclohexanone (100 MHz). 3. 3 CDCI, 1 TMS 200 180 160 140 120 100 80 60 40 PPM (8)
FIG. 22.9
The 1C NMR spectrum of
adlplc acld (22.6 MHz).
CH,CH,CH,CH,
HO
200
180
160
140
120
100
80
60
40
PPM (8)
Transcribed Image Text:FIG. 22.9 The 1C NMR spectrum of adlplc acld (22.6 MHz). CH,CH,CH,CH, HO 200 180 160 140 120 100 80 60 40 PPM (8)
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