For a reaction PCl3 (9) + ICl(g) PCL4I (9) Initially, there are 1.20 mol of phosphorus trichloride, 0.48 moles of iodine monochloride, and 1.26 mol of PCl4l in a 250.0 mL flask. a. What is the value of Q at this point in the reaction? If your answer is a decimal, please include a 0 before the decimal point. type your answer... b. The Keq for this reaction is 50.0. Will the reaction proceed left, right, or is it already at equilibrium? choose your answer... a. If the concentration of PC13 at equilibrium is 4.24M, what is the concentration of iodine monochloride at equilibrium? If your answer is a decimal, please include a 0 before the decimal point. type your answer... M b. If the concentration of PCI3'at equilibrium is 4.24M, what is the concentration of PCI4l at equilibrium? type your answer... M

For a reaction PCl3 (9) + ICl(g) PCL4I (9) Initially, there are 1.20 mol of phosphorus trichloride, 0.48 moles of iodine monochloride, and 1.26 mol of PCl4l in a 250.0 mL flask. a. What is the value of Q at this point in the reaction? If your answer is a decimal, please include a 0 before the decimal point. type your answer... b. The Keq for this reaction is 50.0. Will the reaction proceed left, right, or is it already at equilibrium? choose your answer... a. If the concentration of PC13 at equilibrium is 4.24M, what is the concentration of iodine monochloride at equilibrium? If your answer is a decimal, please include a 0 before the decimal point. type your answer... M b. If the concentration of PCI3'at equilibrium is 4.24M, what is the concentration of PCI4l at equilibrium? type your answer... M

World of Chemistry, 3rd edition

3rd Edition

ISBN:9781133109655

Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste

Chapter9: Chemical Quantities

Section: Chapter Questions

Problem 50A

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The carbon dioxide exhaled in the breath of astronauts is often removed from the spacecraft by reaction with lithium hydroxide 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(l) Estimate the grams of lithium hydroxide required per astronaut per day. Assume that each astronaut requires 2.50 103 kcal of energy per day. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 2.50 103 kcal of heat, calculate the amount of CO2 produced and hence the amount of LiOH required. The H for glucose(s) is 1273 kJ/mol.
list at least three quantities that must be conserved in chemical reactions.
Ethanol, C2H5OH, is a gasoline additive that can be produced by fermentation of glucose. C6H12O62C2H5OH+2CO2 (a) Calculate the mass (g) of ethanol produced by the fermentation of 1.000 lb glucose. (b) Gasohol is a mixture of 10.00 mL ethanol per 90.00 mL gasoline. Calculate the mass (in g) of glucose required to produce the ethanol in 1.00 gal gasohol. Density of ethanol = 0.785 g/mL. (c) By 2022, the U. S. Energy Independence and Security Act calls for annual production of 3.6 1010 gal of ethanol, no more than 40% of it produced by fermentation of corn. Fermentation of 1 ton (2.2 103 lb) of corn yields approximately 106 gal of ethanol. The average corn yield in the United States is about 2.1 105 lb per 1.0 105 m2. Calculate the acreage (in m2) required to raise corn solely for ethanol production in 2022 in the United States.
A soft drink contains an unknown mass of citric acid, C3H5O(COOH)3. It requires 6.42 mL of 9.580 × 10−2-M NaOH to neutralize the citric acid in 10.0 mL of the soft drink. C3H5O(COOH)3(aq) + 3 NaOH(aq) → Na3C3H5O(COO)3(aq) + 3 H2O(ℓ) Determine which step in these calculations for the mass of citric acid in 1 mL soft drink is incorrect? Why? n (NaOH) = (6.42 mL)(1L/1000 mL)(9.580 × 10−2 mol/L) n (citric acid) = (6.15 × 10−4 mol NaOH) × (3 mol citric acid/1 mol NaOH) m (citric acid in sample) = (1.85 × 10−3 mol citric acid) × (192.12 g/mol citric acid) m (citric acid in 1 mL soft drink) = (0.354 g citric acid)/(10 mL soft drink) Determine the correct result.
What mass of solid NaOH (97.0% NaOH by mass) is required to prepare 1.00 L of a 10.0% solution of NaOH by mass? The density of the 10.0% solution is 1.109 g/mL.
On Easter Sunday, April 3, 1983, nitric acid spilled from a tank car near downtown Denver, Colorado. The spill was neutralized with sodium carbonate: 2HNO3(aq)+Na2CO3(aq)2NaNO3(aq)+H2O(l)+CO2(g) a. Calculate H for this reaction. Approximately 2.0 104 gal nitric acid was spilled. Assume that the acid was an aqueous solution containing 70.0% HNO3 by mass with a density of 1.42 glcm3. What mass of sodium carbonate was required for complete neutralization of the spill, and what quantity of heat was evolved? (Hf for NaNO3(aq) = 467 kJ/mol) b. According to The Denver Post for April 4, 1983, authorities feared that dangerous air pollution might occur during the neutralization. Considering the magnitude of H, what was their major concern?
4.6 Use the web to research prices of gasoline at the pump for consumers in your area during the past year. Also find information about the price of crude oil for the same period. Discuss any correlations you observe between the two prices.
Consider the chemical reaction 2 S + 3 O2 → 2 SO3. If the reaction is run by adding S indefinitely to a fixed amount of O2, which of these graphs best represents the formation of SO3? Explain your choice.
3.82 The particulate scale drawing shown depicts the products of a reaction between N2 and O2 molecules. (a) Draw a similar representation for the reactants that must have been present before the reaction took place. (b) Write a balanced chemical equation for the reaction, using the smallest possible whole number coefficients.
Determine the volume of sodium hydroxide solution needed to prepare 26.2 g sodium phosphate, Na3PO4, by the reaction 3NaOH(aq)+H3PO4(aq)Na3PO4(aq)+3H2O(l) The sodium hydroxide solution, whose density is 1.133 g/mL, contains 12.0% NaOH by mass.
94. Baking soda (sodium hydrogen carbonate. NaHCO3) is often used to neutralize spills of acids on the benchtop in the laboratory. What mass of NaHCO3 would be needed to neutralize a spill consisting of 25.2 mL of 6.01 M hydrochloric acid solution?