Give the major organic product(s) of each of the following reactions or sequences of reactions (Show all relevant stereochemistry) and indicate the mechanism of the reaction (S1, S2, El or E2) Reaction Product Mechanism Кон Br DMSO TSO CH Nal acetone CH,CH,ONa* ethanol NH, ONa NASH DMSO
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- divls depends oin the moisture content of the reaction mixture. Propose a detailed mechanism for ench of the following steps to account for the observed The outeome of oxidation of alkenes with 1odine and silver acetate to afford stereochemistry of the product HO () 2, 2 RCO2Ag (i1) NaOH (aq) HO HO () 2, RCO2Ag, H20 (11) NaOH (aq) HOThe following presented reaction scheme lead to the synthesis of which major product from benzene assuming separation of products is possible? 1 NaOH CI. Product Product HSO 2 H,0 FeCl OA Meta-Chlorophenol U& para-ChloroSulfenic acid 6C Para-Chlorophenol 0O Mela chioroaniline1) Complete the following reaction scheme. Show stereochemistry where necessary. Show all organic products. NBS UV 2) (a)Complete the following reaction scheme. Show stereochemistry where necessary b) Indicate the reaction type, SN1, SN2, E1 or E2 (c) Provide two reasons for the reaction type stated in (b) Reacton Pd Penon 2 Reacten Produd Feson2 Reaction Podet Reson 2 Peaction Product Reason 2 Tre OH Peacton Preduct aton Reason1 Reason2 HBr OH 3) For each of the following planar (flat) structures, indicate whether the structure is aromatic or non-aromatic он
- Identify the structure of the product in the following reaction. Provide a suitable mechanism with proper justification OTs TMS Cs,Co, NHTS Tetracyclic Compound C23H21NO2S Ph Me Of 18-crown-6 Mol. wt. 375(a) Provide the missing reagents and line structures of the products (C- E) for the following reactions. Include stereochemistry for products Cand E as indicated. No mechanisms are required. (5) C H,0 Show stereochemistry any one diastereomer OH PCC. CH;Cla D H. Pd/C Show stereochemistry any one enantlomer7. Give the major organic product(s) of the following reactions or sequences of reactions. Show all relevant stereochemistry. (a) OH CO, HSO, H2O, acetone (b) %3| COH 1.LIAIH , ether 2. Но (c) H. 1. NABH4, ethanol 2. Но*
- What is the major organic product obtained from the following reaction? Hint: Be mindful of the stereochemistry which is reflective in selecting the answer. O only 1 O only 2 O only 3 CH3CO3H 2 ས། swowu ' 1 ·!,v:,、 O both 2 and 3 A 3 H(1)Reaction Completion For each of the following reactions, provide the structure(s) of the corresponding product(s). If more than one product is possible, indicate which product is the major product. Also, when relevant, indicate the stereochemistry of your products. H2SO4 (a) ОН heat OK CH3 CI (b) ОН H2SO4 (c) heat HBr (d) 1. ВНз 2. НаОр, NaOн Cl2 (f) CH3OH H2 (g) pd Br2 (1) 1. O3 2. H20 1. NaNH2 (excess) (i) 2. H20 CIChemistry 3. Complete the following reaction scheme. Give all product(s) and indicate major or minor and any relevant stereochemistry. (а) NaOEt heat (b) heat (c) Br NaCN DMF (d) (e) OH H,SO,/H,PO, heat (f) HBr (g) 1) BH. THE 2) H,0, OH (h) 1) Hg(OAC), H-0 2) NaBH, (i) KMNO, NaOH Cold
- For each of the reactions shown below, draw the structure of the major organic product(s) or starting material. Give only one structure per box and indicate stereochemistry where applicable. CH3 NaSH (a) H- -Br H- -OCH3 acetone CH2CH3 (b) (c) fo (d) 3 Br Br₂/light NaOtBu tBuOH OH H₂O monobrominated product monobrominated productOzonolysis of compound D will produce compound E and compound F as products. Hydrationof compound D will produce compound G as major product. Compound D is a major productobtained from dehydrohalogenation of 2-chloro-3-methylbutane. a) Identify the structural formula for compound D, E, F and G.b) Suggest suitable reagent(s) and condition(s) needed for dehydrohalogenation of 2-chloro-3-methylbutane(b) acid, HNO3 to produce compound L. The reaction of compound L with bromine, Br2 in the presence of iron tribromide, FeBr3 produced compound M. Benzene also undergoes Fridel-crafts alkylation reaction with chloroethane, CH;CH2CI using catalyst N to produce compound P. Benzene, CeHe undergoes substitution reaction with concentrated nitric Benzena, CsHe menjalani tindak balas penukargantian dengan asid nitrik, HNO, pekat untuk menghasilkan sebatian L. Tindak balas sebatian L dengan bromin, Brz dengan kehadiran ferum tribromida, FeBrs menghasilkan sebatian M. Benzena juga menjalani tindak balas alkilasi Fridel-crafts dengan kloroetana, CH3CH2CI dengan menggunakan pemangkin N untuk menghasilkan sebatian P. (i) Draw the structural formula of L, M and P. Lukiskan formula struktur bagi sebatian L, M dan P. (ii) State catalyst N. Nyatakan pemangkin N. (iii) Show the formation of electrophile that will be reacted with benzene for the formation of compound P.