Given the following ionic equilibria and their K values:                            AgBr(s)  ⇌  Ag+(aq)  +  Br–(aq);    Ksp = 5.0 x 10–13             Ag+(aq)  +  2NH3(aq)  ⇌  Ag(NH3)2+(aq);     Kf = 1.7 x 107          What is Kc for the following equilibrium?               AgBr(s)  +  2NH3(aq)  ⇌  Ag(NH3)2+(aq)  + Br–(aq);

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter5: Introduction To Chemical Equilibrium
Section: Chapter Questions
Problem 5.49E: 5.49. Consider the following equilibrium: What is the effect on the equilibrium of each of the...
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Given the following ionic equilibria and their K values:

                           AgBr(s)  ⇌  Ag+(aq)  +  Br(aq);    Ksp = 5.0 x 10–13

            Ag+(aq)  +  2NH3(aq)  ⇌  Ag(NH3)2+(aq);     Kf = 1.7 x 107

         What is Kc for the following equilibrium?  

            AgBr(s)  +  2NH3(aq)  ⇌  Ag(NH3)2+(aq)  + Br(aq);

         (A) 8.5 x 10–6

         (B) 2.9 x 10–20

         (C) 3.4 x 1019

         (D) 1.7 x 107

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