Guide to Analysis: [1] This is the combined class NMR sample [2] The sharp singlet at 7.26 = CDC13 [3] In your lab report: use SDBS to assign peaks a, b, c, and d in the spectrum shown below. "d" is a very broad singlet (Note: SDBS predicts"d" at a different location) [4] The NMR predictor "NMRDB" is not useful with this molecule. It assumes the "halves" of benzimidazole act differently and wrongly predicts the aromatic CHs.

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
ChapterL4: Proton (1h) Nmr Spectroscopy
Section: Chapter Questions
Problem 23CTQ
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Guide to Analysis:
[1] This is the combined class NMR sample
[2] The sharp singlet at 7.26 = CDC13
[3] In your lab report: use SDBS to assign peaks a, b, c, and d in the spectrum shown below.
"d" is a very broad singlet (Note: SDBS predicts "d" at a different location)
[4] The NMR predictor "NMRDB" is not useful with this molecule.
It assumes the "halves" of benzimidazole act differently and wrongly predicts the aromatic CHs.
1.0
a
0.9
0.8
0.7
CDC13
solvent
C
TMS
1.00 1.91 2.45
U
…………….
4.5
6.5
3.0
8.0
4.0
2.5
2.0
7.5
3.5
Chemical Shift (ppm)
Normalized Intensity
0.3
0.2
0.13
0
8.5
7.0
6.0
5.5
d
0.91
5.0
1.5
1.0
0.5
-0.0000
0
Transcribed Image Text:Guide to Analysis: [1] This is the combined class NMR sample [2] The sharp singlet at 7.26 = CDC13 [3] In your lab report: use SDBS to assign peaks a, b, c, and d in the spectrum shown below. "d" is a very broad singlet (Note: SDBS predicts "d" at a different location) [4] The NMR predictor "NMRDB" is not useful with this molecule. It assumes the "halves" of benzimidazole act differently and wrongly predicts the aromatic CHs. 1.0 a 0.9 0.8 0.7 CDC13 solvent C TMS 1.00 1.91 2.45 U ……………. 4.5 6.5 3.0 8.0 4.0 2.5 2.0 7.5 3.5 Chemical Shift (ppm) Normalized Intensity 0.3 0.2 0.13 0 8.5 7.0 6.0 5.5 d 0.91 5.0 1.5 1.0 0.5 -0.0000 0
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