Highlight each of the positions on the benzene ring that you expect will be most likely to react by electrophilic aromatic substitution. ☑ .SO₂H CH3 ☑
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- Highlight each of the positions on the benzene ring that you expect will be most likely to react by electrophilic aromatic substitution. O₂N. OHThe compound below can be prepared with an alkyl iodide and a suitable nucleophile. Identify the alkyl iodide and the nucleophile that you would use. For an anionic nucleophile, you do not need to draw the counterion. Alkyl iodide: OH Draw Your Solution Nucleophile: Draw Your Solution SUPPORTFor the given molecule, highlight any nucleophilic sites in red and any electrophilic sites in blue. O: 439 0-H
- Explain why quinuclidine is a much more reactive nucleophile than triethylamine, even though both compounds have N atoms surrounded by three R groups.Explain why quinuclidine is a much more reactive nucleophile thantriethylamine, even though both compounds have N atoms surroundedby three R groups.For each of the molecules below, highlight each of the positions on the benzene ring that you expect will be most reactive towards electrophilic aromatic substitution. HN & bo HO X
- Electrophilic aromatic substitutions proceed in two stages. 1. Attack of the aromatic ring on the electrophile. 2. Regeneration of the stable aromatic system by loss of a positively charged unit, usually a proton. Br Br₂/FeBr3 Draw one resonance structure for the intermediate formed when the electrophile is attacked by benzene in the reaction above. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading.Electrophilic aromatic substitutions proceed in two stages. 1. Attack of the aromatic ring on the electrophile. 2. Regeneration of the stable aromatic system by loss of a positively charged unit, usually a proton. Br Br₂/FeBr3 Draw one resonance structure for the intermediate formed when the electrophile is attacked by benzene in the reaction above. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. (+) ChemDoodleⓇElectrophilic aromatic substitutions proceed in two stages. 1. Attack of the electrophile on the aromatic ring. 2. Regeneration of the stable aromatic system by loss of a positively charged unit, usually a proton. Br FeBr3 Draw the most stable resonance structure for the intermediate that forms by electrophilic attack on ethylbenzene in the reaction above.
- The compound below can be prepared with an alkyl iodide and a suitable nucleophile. Identify the alkyl iodide and the nucleophile that you would use. For an anionic nucleophile, you do not need to draw the counterion.Acyl transfer (nucleophilic substitution at carbonyl) reactions proceed in two stages via a "tetrahedral intermediate." Draw the tetrahedral intermediate as it is first formed in the following reaction. CH3OH H3C CI • • • • You do not have to consider stereochemistry. Include all valence lone pairs in your answer. Do not include counter-ions, e.g., Na+, I", in your answer. In cases where there is more than one answer, just draw one.Decide which compounds from the list below are best suited for nucleophilic addition reactions and which ones are more appropriate for nucleophilic substitution reactions.