Hybridization is an energy requiring process ,yet it occurs, why? Discuss shape of the following [cu(NH3)4]*+ and [Ni(CN)4]*-2

Hybridization is an energy requiring process ,yet it occurs, why? Discuss shape of the following [cu(NH3)4]+ and [Ni(CN)4]-2

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter19: Complex Ions

Section: Chapter Questions

Problem 39QAP

See similar textbooks

Related questions

Q: Use crystal field theory to work out the d-orbital splittings and electron occupancy for the…

Q: Which of the reagents would oxidize Cr to Cr +, but not Fe to Fe3+? Со Са Br Br, Ca²+ Co2+

Q: Determine the charge of the metal center in diaquadibromoplatinum, [Pt(H2O)2Br2] a. Draw the…

A: The given complex is diaquadibromoplatinum, [Pt(H2O)2Br2]. In this complex, the central metal ion…

Q: Determine the charge of the metal center in tetraamminedichloroiron, [Fe(NH3)4Cl2] a. draw the…

Q: Determine the charge of the metal centre in tetraamminedichloroiron, [Fe(NH3)4Cl2] . a.Draw the…

Q: Hexafluorocobaltate(III) ion is a high-spin complex. Draw the orbital-energy splitting diagram for…

A: A coordination bond is a type of covalent bond that is formed by unequal sharing of electrons…

Q: What are the charge and coordination number of the central metal ion(s) in each compound of Give…

A: Coordination complexes are assigned the names according to the set of rules assigned in the…

Q: For the low spin coordination compound [Fe(en)2Cl]Cl, identify the Oxidation number of iron

A: Note : I think the complex should [Fe(en)2Cl2]Cl. So I'm giving answer for both the complex.

Q: Draw the Lewis diagrams for each ligand. Indicate the lone pair(s) that may be donated to the metal.…

A: Lewis diagram- Represents the bonding between atoms of a molecule and the lone pairs in the…

Q: Name the following metal complexes or complex ions: formula name [FeCi, (co).]

A: Complex ion consist of metal and several ligand within the coordination sphere Here we are required…

Q: Determine if each of the following metal complexes is chiral and therefore has an optical isomer:…

A: a.

Q: What is the coordination number of the central metal in [Cr(acac)3] ? The acac ligand can be…

A: Coordination number of the central metal which is Chromium in [Cr(acac)3] is 6.

Q: Explain the differences between high-spin and low-spin metal complexes.

A: Complexes with weak field ligands have the same number of unpaired electrons as the free metal ion…

Q: Determine the name of the following complexes and give the coordination number of the central metal…

Q: Determine the LFSE in terms of Δ and P for the following complex ions. Be sure to draw the…

Q: How many unpaired electrons are there in a high-spin octahedral Fe2+ complex? A diagram will likely…

A: Octahedral Fe2+ complex:

Q: Identify each of the following coordination complexes as either diamagnetic or paramagnetic: (a)…

A: a) The given compound is [V(H2O)6]3+ The Oxidation state of ‘V’ is +3. The electronic configuration…

Q: 1. In coordination compound [Cr(en)2Cla]Cl the ligands the the coordination number is the donor…

A: In the coordination compound [Cr(en)2Cl2]Cl , the central metal atom is Cr and the ligands are…

Q: a) Draw the structure and the systematic name of the following d-metal complexes: (0) [Mn(CO),H₂]…

A: As per the rules only the first three subparts of the first question can be answered

Q: Determine the charge of the metal center in diaquadibromoplatinum, [Pt(H2O)2Br2]. a.Draw the…

A: Geometrical isomers are the type of stereoisomers in which the species have same molecular formula…

Q: Aqueous solutions of [Mn(H2O)6]2+ are faint pink, so much so that they appear to be colorless, which…

A: Introduction: The color of 3d transition metal ion in the solution is mainly because of two…

Q: Identify each of the following coordination complexes as either diamagnetic or paramagnetic.…

A: To determine magnetic behavior of complexes:The following coordination complexes area). (Ag…

Q: Explain why [FeF6]³- is colorless whereas [COF6]³- is colored but exhibits only a single band in the…

A: The ligands which produces greater splitting in d orbitals are known as strong field ligands. The…

Q: Why is CO a stronger ligand than Cl-?

A: The spectrochemical series is a list of ligands based on the strength of their interaction with…

Q: Identify each of the following coordination complexes as either diamagnetic or paramagnetic: (a)…

Q: The coordination complex [Cr(CO)6] forms colorless, diamagnetic crystals that melt at 90 °C. What is…

A: The oxidation number of chromium in Cr(CO)6 has to be given.

Q: Give the systematic name of this coordination compound. K,[Fe(CN),l

A: As formula has 6 CN So, hexacyano Fe so, ferrate(III)

Q: Vanadium may have been used by some ancient animals ____________.

A: A number of species of marine algae produce vanadium bromoperoxidase as well as the closely related…

Q: Would it be better to use octahedral complexes of Cr3+ or Co3+ to determine whether a given ligand…

A: In order to decide the strength of ligands, the following factors have to check; The electronic…

Q: Explain why tetrahedral complexes are mostly low-spin or high-spin.

A: The central atom in the tetrahedral geometry is linked to four surrounding atoms. All of these are…

Q: [CoF6]3- absorbs 700 nm (red) radiation whereas [Co(H2O)6]3+ absorbs 600 nm (orange) radiation.…

A: The crystal field energy diagram f the given complexes is drawn as follows:

Q: Given that the cyanide ion is a high field ligand, determine the electron structure of [Co(CN)6]4…

A: CN is strong field ligand and behaves as a low spin find the oxidation state , and fill the…

Q: Based on crystal field theory, please write the d-orbital energy diagrams in the Following…

A: The Crystal Field Theory (CFT) is a model for the bonding interaction between transition metals and…

Q: 4. Using crystal field theory, prove [NiCla]²- is a tetrahedral paramagnetic complex.

A: The given complex is NiCl42-, has nickel metal as the central metal atom and the ligands are four…

Q: Explain the following observations :(i) Copper atom has completely filled d orbitals (3d10) in its…

A: The elements in which the last electron is filled in d sub shell are known as transition elements.

Q: Determine the oxidation state and coordination number of the metal ion in each complex ion. a.…

A: To solve the given problems related to coordination compounds, we must be aware of the following…

Q: What is required of Lewis bases to act as ligands in coordination compounds?

A: Lewis base is a species which can donate electron pair to a Lewis acid.

Q: Give the IUPAC name for this coordination compound. [Cr(H, O),CIJSO4

A: Write IUPAC name of the given coordination compound-

Q: The complex [Fe(CO)6]+2 exhibits π-acceptor behavior. Using ligand field theory, draw the molecular…

A: Ligand field theory is the theory which includes both the ionic and covalent bonding of the…

Q: Why are there both high-spin and low-spin octahedral com-plexes but only high-spin tetrahedral…

Q: Fluoride ion ranks low in the spectrochemical series and produces a weak crystal field in complex…

A: Given, Coordination complex = CoF64- F- = Weak field ligand Number of unpaired electrons in…

Q: Identify each of the following coordination complexes as either diamagnetic or paramagnetic: (a)…

Q: Name these coordination compounds. formula name Na, [CrCI, (H,0)] Br *[FeBr, (CO),]

Q: How many ligands are found on the coordination compound: [Co(NH3)5CI]Cl2 ? O A. 8 B. 6 O C.4 O D.5

A: How many ligand found in the given complex ?

Q: If this is the only place in the visible spectrum where the complex absorbs light, what color would…

A: When a complex absorbs all the visible light except one then the one which is not absorbed by the…

Concept explainers

Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.

Question

Hybridization is an energy requiring process ,yet it occurs, why? Discuss shape of the following [cu(NH3)4]*+ and [Ni(CN)4]*-2

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step 3

VIEW

Step by step

Solved in 3 steps

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Q. Hybridization is an energy requiring process, yet it occurs, why? Discuss shape of the following: [Cu (NH3)4] + and [Ni (CN)4]-2
Consider the reactions 1. [Cr(H2O)6]** + [C©CI(NH3)s]* → [Co(NH3)s(H2O)]²* + [CrCl(H2O)s]** 2. [Fe(CN)6]* + [Mo(CN)s]-→ [Fe(CN)6]³¯ + [Mo(CN)8]* Which one of the following is the correct statement? (i) Both involve an inner sphere mechanism (ii) Both involve an outer sphere mechanism (iii) Reaction 1 follows inner sphere and reaction 2 follows outer sphere mechanism (iv) Reaction 1 follows outer sphere and reaction 2 follows inner sphere mechanism (A) i (B) ii (C) iv (D) ii
Give evidence that [Co(NH3)5Cl]SO4 and [Co(NH3)5SO4]Cl are ionization isomers.(ii). Calculate magnetic moment for the [Fe(H2O)6]3+ and [Fe(CN)6]3−, which one show strong paramagnetic behavior- Explain?
[CuCl4]2− is green. [Cu(H2O)6]2+is blue. Which absorbs higher-energy photons? Which is predicted to have a larger crystal field splitting?
Hi! I tried this and it seemed wrong and was curious if it could be [Fe(CN)6]3-?
How would you draw the isomer structure(s) for [Cr(en)2BrCl] 1+
In [Cr(NH₃)₆]Cl₃, the [Cr(NH₃)₆]³⁺ ion absorbs visiblelight in the blue-violet range, and the compound is yellow-orange. In [Cr(H₂O)₆]Br₃, the [Cr(H₂O)₆]³⁺ ion absorbs visiblelight in the red range, and the compound is blue-gray. Explain these differences in light absorbed and color of the compound
[Cu (NH3) 4] SO4.H2O Draw all isomer structures.
Assign a systematic name to each of the following chemical compounds. Compound Name (a) Na[Mn(CN)5l fill in the blank 1 (b) [Cu(bipy)2l]NO3 fill in the blank 2 (c) [Fe(CO)5] fill in the blank 3 (d) [Cr(NH3)3(CN)3] fill in the blank 4
Which is more acidic and why? [Fe(H2O)6]2+ or [Fe(NH3)(H2O)5]2+
Uses crystal field theory (CCT) to predict the number of unpaired electrons in the following compounds. Indicate if the compound is diamagnetic or paramagnetic: a) [Fe(H2O)s]Cl, b) [Os(en)3]Cl2 c) Ka[Fe(CN)s] d) [Mn(acac)2(H20)2]SO4
3. Consider the blue-colored compound, [Cr(H₂O)]3³ and the yellow-colored compound, [Cr(CN)6]³. Calculate their magnetic moments and discuss their magnetic properties and their color.