i Claisen condensation between a diethyl ester and an ethyl ester followed by saponification, acidification, and decarboxylation forms a diketone. Work out this synthesis on a separate sheet of paper, and then draw the structure of compound a. COOEt COOEt 1. Eto Na+ 2. HCI, H₂0 compound a • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • Do not include counter-ions, e.g., Na*, I', in your answer. NaOH, H₂O Heat compound b HCI, H₂O Heat compound c (CgH1202)

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter7: Cycloalkanes
Section: Chapter Questions
Problem 15E
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COOEt
COOEt
1. Eto Na+
2. HCI, H₂O
compound a
NaOH, H₂O
Heat
• You do not have to consider stereochemistry.
• You do not have to explicitly draw H atoms.
• Do not include lone pairs in your answer. They will not be considered in the grading.
• Do not include counter-ions, e.g., Na+, I, in your answer.
compound b
HCI, H₂O
Heat
Claisen condensation between a diethyl ester and an ethyl ester followed by saponification, acidification, and decarboxylation forms a diketone.
Work out this synthesis on a separate sheet of paper, and then draw the structure of compound a.
compound c (C9H12O2)
Transcribed Image Text:COOEt COOEt 1. Eto Na+ 2. HCI, H₂O compound a NaOH, H₂O Heat • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • Do not include counter-ions, e.g., Na+, I, in your answer. compound b HCI, H₂O Heat Claisen condensation between a diethyl ester and an ethyl ester followed by saponification, acidification, and decarboxylation forms a diketone. Work out this synthesis on a separate sheet of paper, and then draw the structure of compound a. compound c (C9H12O2)
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