Identify the MAJOR product formed in this sequence of reactions. Note: enantiomers, when formed, are omitted. Bonus: which of these products are chiral? Br 1) t-BuOK, t-BuOH 2) m-CPBA m-CPBA .OH A B C D E
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- Draw the major organic product that results in the following reaction. Include stereochemistry at the chiral center. M OH 120 1. TsCl, Pyr 2. NaCNWhat product(s) is(are) formed in the following reaction Br/CH-Clz Br plus enantiomer H3C Et Br Br H and H3C Br H3C Et Et Br он ...Et plus enantiomer H3C BrIs the product of the reaction below optically active? hv Br₂ OYes, because the reaction produces an optically active product with a chiral center. O No, because the reaction produces a mixture of optically active enantiomers. OYes, because the reaction produces an optically active product with a Br on a terminal carbon. O No, because it is impossible to predict where B r will be added. O No, because the reaction produces a meso compound.
- Which is the better method to synthesize n-propylbenzene? A) B) CH3CH₂-C-CI AICI; CH3CH₂-CH₂-CI AICI; CH₂-CH3 CH₂ Zn (Hg) HC1 CH₂-CH₂ CH₂ CH₂-CHWhich carbocation is the most stabilized? Me Me CO₂Me MeO A B C D Select an answer and submit. For keyboard navigation, use the up/down arrow keys to select an answer. a A b B CC OMe Me Me OMe Me Me MeO. OMe E Me MeDraw the major organic product of each reaction. Indicate the stereochemistry at the stereogenic center. Omit byproducts such as salts. If applicable, expand octets to minimize formal charges. CH3S SOCIl2 Product A Product B pyridine D HO, CH3S- TSCI Product C Product D pyridine
- When norbornene undergoes hydroboration-oxidation, a mixture of two stereoisomers is produced in a roughly 6:1 ratio. (a) Draw both of these isomeric products. (b) Which product is favored? Hint: You should build a model of norbornene and consider the transition state leading to each product. 1. BH3 THF ? 2. H2O2, NaOH, H,O NorborneneDraw all four bonds at chiral centers. Draw the major product predicted for the following reaction. ..OTS OCH3 25 °C2. What products would be obtained by treating A-D with NaOt-Bu in t-BuOH? Explain your reasoning, and if more than one product forms, indicate which product is major. Br A Br B C لي Br D
- CH3 CI-s-CH3 1. + N(CH2CH3)3 ? 2. NaSCH2CH3 НО Predict the product(s) that will form in the reaction scheme above. Select the answer below that describes the product(s): A single achiral product forms A single chiral product forms Two achiral products form, and they are constitutional isomers Two achiral products form, and they are diastereomers Two achiral products form, and they are unrelated to each other Two chiral products form, and they are constitutional isomers Two chiral products form, and they are diastereomers Two chiral products form, and they are enantiomers Two chiral products form, and they are unrelated to each other Three or more achiral products form Three or more chiral products formThe two pentene isomers react with mCPBA, followed by an aqueous workup with NaOH/H2Ó. Draw the key reaction intermediates and the product(s); use arrow pushing to explain the stereochemical outcomes of the reactions Intermediate Final Products MCPBA CO2OH mCPBA NaOH/H2O CI Intermediate Final Products MCPBA NaOH/H2O 6.1. Wat is het product van de volgende driestapsreactie (gebruik de correcte stereochemie): 1) NaNH2 2) CH3Br 3) H2 + Lindlar katalysator
