Identify the structure of the important fragments. Show the arrow pushing mechanism to form the significantfragments. Suggest possible structure based on MS and IR data.1. MF C3H,NO100 -15.01.518.01.427.01.928.02.480 -30.01.838.01.539.02.350.010.951.031.452.02.853.51.16058.03.974.03.575.02.776.04.577.087.278.07.940105.0100.0106.08.5134.032.4135.038.4136.03.620 -255075100125m/zRelative Intensity

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Identify the structure of the important fragments. Show the arrow pushing mechanism to form the significant fragments. Suggest possible structure based on MS and IR data. 1. MF CH,NO ---

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter20: Dienes, Conjugated Systems, And Pericyclic Reactions

Section: Chapter Questions

Problem 20.25P

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Concept explainers

Mass Spectrometry

This process is an instrumental method in which a sample is changed to fast moving positive ions by electron bombardment. The charged particles vary due to their different mass to charge ratio and are estimated with the help of this difference. It is also called mass spectroscopy.

Question

100%

Identify the structure of the important fragments. Show the arrow pushing mechanism to form the significant
fragments. Suggest possible structure based on MS and IR data.
1. MF C3H,NO
100 -
15.0
1.5
18.0
1.4
27.0
1.9
28.0
2.4
80 -
30.0
1.8
38.0
1.5
39.0
2.3
50.0
10.9
51.0
31.4
52.0
2.8
53.5
1.1
60
58.0
3.9
74.0
3.5
75.0
2.7
76.0
4.5
77.0
87.2
78.0
7.9
40
105.0
100.0
106.0
8.5
134.0
32.4
135.0
38.4
136.0
3.6
20 -
25
50
75
100
125
m/z
Relative Intensity

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