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Indicate the reagent(s) needed to carry out the following transformations. a) он OTs b) но

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter22: Carbonyl Alpha-substitution Reactions

Section22.SE: Something Extra

Problem 26MP: Nonconjugated , -unsaturated ketones, such as 3-cyclohexenone, are in an acid-catalyzed equilibrium...

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Concept explainers

Designing a Synthesis

Organic synthesis is a branch of chemical synthesis that involves the planned construction of organic compounds/molecules from smaller units that possess functional groups. Friedrich Wöhler was the first scientist who designed the synthesis of an organic compound, urea from inorganic starting materials silver cyanate with ammonium chloride via a simple, one-step synthesis.

Question

REACTIONS
Indicate the reagent(s) needed to carry out the following transformations.
a)
он
COTS
b)
он

Expert Solution

Step 1

NOTE : In the 2nd reaction, the H atom is present in the product attached to the carbon making double bond O and its now showing in the pic due to cropping error.

Hence I'm taking it as an aldehyde only.

The reactions given are,

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