Isomerisation of [Co(NH3);NO2]Cl2 (Nitro) to [Co(NH;};ONO]CI, has been studied extensively using IR spectroscopy- Kinetic data Time (da) Absorbance (a) A A 0.480 0.462 0.414 0.349 0.283 0.156 0.118 0.108 0.372 0.354 0.306 0.241 0.175 0.048 0.010 0.125 0.500 2.0 4.0 11.0 18.0 8. ... Absorbance measured at 1055 cm!. Using this information answer question 1-4 below 1 Suggest why 1060cm was chosen as the monitoring wavelength 2 Suggest what is causing the decrease in absorption at this wayelength

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Answer part i ii
Isomerisation of [Co(NH3);NO2]Cl2 (Nitro) to [Co(NH;);ONO]Cl, has been studied
extensively using IR spectroscopy.
Kinetic data
Time
Absorbance
(da)
(a).
A - A
0.480
0.462
0.414
0.349
0.283
0.156
0.372
0.354
0.306
0.241
0.175
0.048
0.010
0.125
0.500
2.0
4.0
11.0
18.0
0.118
0.108
8.
...
Absorbance measured at 1055 cm.
Using this information answer question 1-4 below
1 Suggest why 1060cm was chosen as the monitoring wavelength
2 Suggest what is causing the decrease in absorption at this wavelength
Dete
Transcribed Image Text:Isomerisation of [Co(NH3);NO2]Cl2 (Nitro) to [Co(NH;);ONO]Cl, has been studied extensively using IR spectroscopy. Kinetic data Time Absorbance (da) (a). A - A 0.480 0.462 0.414 0.349 0.283 0.156 0.372 0.354 0.306 0.241 0.175 0.048 0.010 0.125 0.500 2.0 4.0 11.0 18.0 0.118 0.108 8. ... Absorbance measured at 1055 cm. Using this information answer question 1-4 below 1 Suggest why 1060cm was chosen as the monitoring wavelength 2 Suggest what is causing the decrease in absorption at this wavelength Dete
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