What is this reaction's mechanism? NLoPhRuCl₂ (PPh 3), K₂ (03CH3OH, 40 bar H₂NPh

In the first step, the three-membered ring with a nitrogen atom (aziridine) reacts with a silane…

Answered: N Lo Ph RuCl₂ (PPh 3), K₂ (03 CH3OH, 40…

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N Lo Ph RuCl₂ (PPh 3), K₂ (03 CH3OH, 40 bar H₂ N- Ph

Introduction to General, Organic and Biochemistry

11th Edition

ISBN:9781285869759

Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres

Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres

Chapter6: Solutions And Colloids

Section: Chapter Questions

Problem 6.85P

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Question

What is this reaction's mechanism?

N
Lo
Ph
RuCl₂ (PPh 3), K₂ (03
CH3OH, 40 bar H₂
N
Ph

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Step 1: Ring-Opening of the Three-Membered Ring

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Step 2: Ring-Opening of the Six-Membered Ring

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Step 3: Condensation and Ring-Closure and Cyclization

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