organic 11 12 BUN*Ⓡ* Finish attempt ... 9 10 13 14 Question 1 Not yet answered Flag question Match each set of structures to its place in the synthesis of cyclohexanone oxime from cyclohexanone. The reagents are not balanced and water as a solvent is not include! Interestingly, amines (nitrogen containing compounds like alkaloids, e.g., cocaine, heroine, nicotine, etc.) are often sold as hydrochloride salts because amines readily react with carbon dioxide reversibly forming carbamates (another environmental problem). So in essence we are "freebasing" hydroxylamine hydrochloride like we did caffeine in the first semester. C1- *H₂N-OH H HO OH НО. H НО. H₂N-OH HO `N Nx H OH H H₂O 0 C 0 Nat Cl H₂O Na Cl Nat C1- H₂O 0=C=0 *Na O 0 C 0 H₂O HO Na C1- Na Cl 0 C 0 OH ONa+ Choose... Choose... Choose... Choose... Choose... Choose... 4 Andrea Salas Rivera AS ◆

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter11: Ethers, Epoxides, And Sulfides
Section: Chapter Questions
Problem 11.18P
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12
BUN*Ⓡ*
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9
10
13
14
Question 1
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Match each set of structures to its place in the synthesis of cyclohexanone oxime from cyclohexanone.
The reagents are not balanced and water as a solvent is not include!
Interestingly, amines (nitrogen containing compounds like alkaloids, e.g., cocaine, heroine, nicotine, etc.) are often sold as hydrochloride salts because amines readily react with carbon
dioxide reversibly forming carbamates (another environmental problem). So in essence we are "freebasing" hydroxylamine hydrochloride like we did caffeine in the first semester.
C1-
*H₂N-OH
H
HO
OH
НО.
H
НО.
H₂N-OH
HO
`N
Nx
H
OH
H
H₂O
0 C 0
Nat Cl
H₂O
Na Cl
Nat C1-
H₂O
0=C=0
*Na O
0 C 0
H₂O
HO
Na C1-
Na Cl
0 C 0
OH
ONa+
Choose...
Choose...
Choose...
Choose...
Choose...
Choose...
4 Andrea Salas Rivera AS
◆
Transcribed Image Text:organic 11 12 BUN*Ⓡ* Finish attempt ... 9 10 13 14 Question 1 Not yet answered Flag question Match each set of structures to its place in the synthesis of cyclohexanone oxime from cyclohexanone. The reagents are not balanced and water as a solvent is not include! Interestingly, amines (nitrogen containing compounds like alkaloids, e.g., cocaine, heroine, nicotine, etc.) are often sold as hydrochloride salts because amines readily react with carbon dioxide reversibly forming carbamates (another environmental problem). So in essence we are "freebasing" hydroxylamine hydrochloride like we did caffeine in the first semester. C1- *H₂N-OH H HO OH НО. H НО. H₂N-OH HO `N Nx H OH H H₂O 0 C 0 Nat Cl H₂O Na Cl Nat C1- H₂O 0=C=0 *Na O 0 C 0 H₂O HO Na C1- Na Cl 0 C 0 OH ONa+ Choose... Choose... Choose... Choose... Choose... Choose... 4 Andrea Salas Rivera AS ◆
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