Part A Consider the titration of 36.4 mL of 0.260 M HF ( K = 3.5 x 10) with 0.220 M NaOH. Calculate the pH at each of the following points. How many milliliters of base are required to reach the equivalence point? Express your answer using three significant figures. VNaOH = mL Submit Previous Answers Bequest Answer X Incorrect; Try Again; 5 attempts remaining Part B Calculate the pH after the addition of 9.10 mL of base Express your answer using two decimal places. pH

Part A Consider the titration of 36.4 mL of 0.260 M HF ( K = 3.5 x 10) with 0.220 M NaOH. Calculate the pH at each of the following points. How many milliliters of base are required to reach the equivalence point? Express your answer using three significant figures. VNaOH = mL Submit Previous Answers Bequest Answer X Incorrect; Try Again; 5 attempts remaining Part B Calculate the pH after the addition of 9.10 mL of base Express your answer using two decimal places. pH

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter14: Equilibria In Acid-base Solutions

Section: Chapter Questions

Problem 43QAP: A solution consisting of 25.00 g NH4Cl in 178 mL of water is titrated with 0.114 M KOH. (a) How many...

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A diprotic acid, H2B(MM=126g/moL), is determined to be a hydrate, H2B xH2O. A 10.00-g sample of this hydrate is dissolved in enough water to make 150.0 mL of solution. Twenty-five milliliters of this solution requires 48.5 mL of 0.425 M NaOH to reach the equivalence point. What is x?
A 0.400-M solution of ammonia was titrated with hydrochloric acid to the equivalence point, where the total volume was 1.50 times the original volume. At what pH does the equivalence point occur?
Sketch the titration curve for a weak acid titrated by a strong base. When performing calculations concerning weak acidstrong base titrations, the general two-slep procedure is to solve a stoichiometry problem first, then to solve an equilibrium problem to determine the pH. What reaction takes place in the stoichiometry part of the problem? What is assumed about this reaction? At the various points in your titration curve, list the major species present after the strong base (NaOH, for example) reacts to completion with the weak acid, HA. What equilibrium problem would you solve at the various points in your titration curve to calculate the pH? Why is pH 7.0 at the equivalence point of a weak acid-strong base titration? Does the pH at the halfway point to equivalence have to be less than 7.0? What does the pH at the halfway point equal? Compare and contrast the titration curves for a strong acidstrong base titration and a weak acidstrong base titration.
A solution consisting of 25.00 g NH4Cl in 178 mL of water is titrated with 0.114 M KOH. (a) How many milliliters of KOH are required to reach the equivalence point? (b) Calculate [Cl-], [K+], [NH3], and [OH-] at the equivalence point. (Assume that volumes are additive.) (c) What is the pH at the equivalence point?
When 40.00 mL of a weak monoprotic acid solution is titrated with 0.100-M NaOH, the equivalence point is reached when 35.00 mL base has been added. After 20.00 mL NaOH solution has been added, the titration mixture has a pH of 5.75. Calculate the ionization constant of the acid.
The titration of Na2CO3 with HCl bas the following qualitative profile: a. Identify the major species in solution at points AF. b. Calculate the pH at the halfway points to equivalence, B and D. (Hint: Refer to Exercise 113.)
What mass of NH4Cl must be added to 0.750 L of a 0.100-M solution of NH3 to give a buffer solution with a pH of 9.26? (Him: Assume a negligible change in volume as the solid is added.)
What is an acidbase indicator? Define the equivalence (stoichiometric) point and the end point of a titration. Why should you choose an indicator so that the two points coincide? Do the pH values of the two points have to be within 0.01 pH unit of each other? Explain.
Sketch a titration curve for the titration of potassium hydroxide with HCl, both 0.100 M. Identify three regions in which a particular chemical species or system dominates the acid-base equilibria.
A sodium hydrogen carbonate-sodium carbonate buffer is to be prepared with a pH of 9.40. (a) What must the [ HCO3 ]/[ CO32 ]ratio be? (b) How many moles of sodium hydrogen carbonate must be added to a liter of 0.225 M Na2CO3 to give this pH? (c) How many grams of sodium carbonate must be added to 475 mL of 0.336 M NaHCO3 to give this pH? (Assume no volume change.) (d) What volume of 0.200 M NaHCO3 must be added to 735 mL of a 0.139 M solution of Na2CO3 to give this pH? (Assume that volumes are additive.)