Predict the major products of the following organic reaction: + NC Δ ? Some important Notes: • Draw the major product, or products, of the reaction in the drawing area below. •If there aren't any products, because no reaction will take place, check the box below the drawing area instead. Be sure to draw bonds carefully to show important geometric relationships between substituents.
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- 1. For an addition reaction, why does free energy, ΔG, becomes more positive with increasing temperature? a. The negative enthalpy dominates at high temperature. b. The positive enthalpy dominates at high temperature. c. The positive entropy dominates at high temperature. d. The negative entropy dominates at high temperature 2. Which of the following alkynes will form only 1 product in acid-catalyzed hydration? a. 2-pentyne b. 3-hexyne c. 3-pentyne d. 1-hexyne 3. Which of the following statements best describes the general reactivity of alkynes? a. An alkyne reacts as an electrophile and is, therefore, electron poor. b. Alkynes undergo electrophilic addition reactions just like alkenes. c. An alkyne reacts as an electrophile and is therefore electron-rich. d. An alkyne reacts as a nucleophile and is therefore electron-poor.Consider the compound 3(S),5,5-trimethyl cyclohexane. Upon reduction with H2 on a 1% Pt/C catalyst, draw the equation for this reaction, find out the absolute configuration of the product and explain why the absolute configuration is completely inverted in this reaction1) Predict the products (if any) that will be formed by the reaction below. If no reaction occurs, write NR after the reaction arrow. 2HClO4(aq)+ Co(s) =
- Phineas and Ferbs, two brothers who enjoy vacations, doing fun things every summer. This summer the brothers and their friends carry out an organic synthesis with an unknown compound (L1) that contains 52% Carbon, 6% Hydrogen and 42% bromine, this compound (L1) is treated with magnesium in ether to obtain L2 , which reacts violently with D2O for 1-methyl cyclohexene with a deuterium atom in the methyl group (L3). The L2 reaction is treated with acetone followed by hydrolysis to give L4. Heating L4 with concentrated sulfuric acid gives L5, which decolors the bromine, obtaining L6. L5 undergoes hydrogenation with excess hydrogen and platinum as a catalyst giving rise to isobutyl cyclohexane. Determine the structures of compounds L1 through L6.What are the reagents used to convert 2-butyne to C4H8? What are the products when that C4H8 is mixed with OsO4, and H2O (the formula will be C4H10O2 racemic)? What is the product when C4H8 is mixed with RCO3H, and H2O (the formula will be C4H10O2 meso)?Which statement best describes the product mixture after (R)-3-chloro-3-methylhexane undergoes an SN1 reaction? a. The product mixture would be 100% R enantiomer b. The product mixture would be 100% S enantiomer c. The product mixture would be racemic d.The product mixture would be 100% cis isomer e.The product mixture would be 100% trans isomer
- The pictured reaction shows an alkyl bromide being converted into an alkene. Choose all reagents that would produce the pictured alkene as the major product. A) NaOH/H2O B) H2O C) tBuOK/tBuOH D) EtONa/EtOHWrite the products of the compound and the following reagents. If the reaction would not work for your compound, write "no reaction" and explain the problem. CrO_3Draw eugenol as a line structure. The double bonds of the benzene ring are fairly unreactive unless you use special catalysts. But the double bond on the side group is reactive. Draw the mechanism of eugenol reacting with HBr to form the two possible carbocation intermediates. Put your intermediates into square brackets. Label each carbocation as a methyl carbon or 1°, 2°, or 3°. Then circle a more stable carbocation if one is more stable. Can you guess what the final product is?
- What is the product of the reaction of 1-hexyne with excess Br2? 1,2-dibromohexene 2,2-dibromohexene 1,1-dibromohexene 1,1,2,2-tetrabromohexane1. Predict the elimination products of the following reactions. When two alkenes are possible, predict which one will be the major product. Explain your answers, showing the degree of substitution of each double bond in the products. 2. Which of these reactions are likely to produce both elimination and substitution products? (a) 2-bromopentane +NaOCH3 (b) 3-bromo-3-methylpentane +NaOMe(Me= methyl, CH3) (c) 2-bromo-3-ethylpentane +NaOH (d) cis-1-bromo-2-methylcyclohexane +NaOEt (Et= ethyl, CH2CH3)Please draw an alkane that has at least one primary, one secondary, and one tertiary carbon. Then take molecule and react it with F^2 (Identify all mono halogenated products for each reaction)