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- Chemical equation when methanal react with in © Chemical equatior when Propanone react with /in , +est O Fehling ® EMn O4 (3 2,4-DNPHWhich of the following structures and IUPAC names are incorrectly matched? * oe (A) Methyleyclohexanoate (В) `NH2 Br 4-Bromo-3-chlorohexanamide 2-Ethoxypentane (D) HOOC HOOC 3,5-Nonanedioic acid В A DThe key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold Helminthosporium sativum, involves the following base treatment of a keto tosylate. What kind of reaction is occurring? How would you complete the synthesis?
- Draw structures corresponding to the following names: (a) Phenyl benzoate (b) N-Ethyl-N-methylbutanamide (c) 2,4-Dimethylpentanoyl chloride (d) Methyl 1-methylcyclohexanecarboxylate (e) Ethyl 3-oxopentanoate (f) Methyl p-bromobenzenethioate (g) Formic propanoic anhydride (h) cis-2-Methylcyclopentanecarbonyl bromideWhat carbonyl compounds might you start with to prepare the Following compounds by Grignard reaction? List all possibilities. (a) 2-Methyl-2-propanol (b) 1-Ethylcyclohexanol (c) 3-Phenyl-3-pentanol (d) 2-Phenyl-2-pentanolStep 2: A hemiacetal formation has a similar mechanism to the hydrate reaction, except 1 equivalent of alcohol is added instead of water. 1² R₂ R₁ LOR3 R₁ R₂ The hemiacetal reaction is also reversible and can also be catalyzed by either acid or base. Hemiacetals are not usually isolated, except in the formation of 5- and 6-membered rings, as often seen in carbohydrate chemistry. Identify the hemiacetal formed from the intramolecular cyclization of the molecule shown. OH H OH R3OH OH OH OH CH₂OH NaOH ?