QNo: treatment treatment of compound F Pylamide followed by Cyclohexane with lithiu gives

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter22: Carbonyl Alpha-substitution Reactions
Section22.SE: Something Extra
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QNo: treatment of compound F with lithium
diisopropylamide followed by cyclohexane gives
either
aldehyde
G OR H. G
is formed if the
at -78°C whereas H
IS
added
is formed
if the
at
Oc. Furthermore
1
aldehyde is added
treatment of G
역어
With
lithium
disopropylamide
at
O°c gives.
#1
Explain these results
CH2=CHCHCN
OCH2CH2O C2H5
F
OH
HO
EN
ĊCH=CH₂
OCH₂CH₂OCH
G
CH₂CH=COCH2CH2O C2H5
CN.
Transcribed Image Text:QNo: treatment of compound F with lithium diisopropylamide followed by cyclohexane gives either aldehyde G OR H. G is formed if the at -78°C whereas H IS added is formed if the at Oc. Furthermore 1 aldehyde is added treatment of G 역어 With lithium disopropylamide at O°c gives. #1 Explain these results CH2=CHCHCN OCH2CH2O C2H5 F OH HO EN ĊCH=CH₂ OCH₂CH₂OCH G CH₂CH=COCH2CH2O C2H5 CN.
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